Crossref journal-article
AIP Publishing
The Journal of Chemical Physics (317)
Abstract

Measurements of infrared spectra obtained with polarized radiation are reported for nylon, silk fibroin, feather rachis, stretched wool, and kangaroo tail tendon before and after reaction with deuterium oxide. In every case except tendon replacement of hydrogen by deuterium in the peptide linkage occurs preferentially in the less well oriented regions of the specimen. A residual absorption band between 4600 and 4650 cm—1 is evident in the partially deuterated protein specimens and it is suggested that this may be assigned to a combination of CH and CO stretching modes.

Bibliography

Fraser, R. D. B., & MacRae, T. P. (1958). Hydrogen →Deuterium Exchange Reaction in Fibrous Proteins. I. The Journal of Chemical Physics, 29(5), 1024–1028.

Authors 2
  1. R. D. B. Fraser (first)
  2. T. P. MacRae (additional)
References 17 Referenced 24
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Dates
Type When
Created 20 years, 7 months ago (Jan. 5, 2005, 9:16 p.m.)
Deposited 1 year, 6 months ago (Feb. 8, 2024, 1:52 p.m.)
Indexed 11 months, 3 weeks ago (Sept. 10, 2024, 10:35 p.m.)
Issued 66 years, 10 months ago (Nov. 1, 1958)
Published 66 years, 10 months ago (Nov. 1, 1958)
Published Print 66 years, 10 months ago (Nov. 1, 1958)
Funders 0

None

@article{Fraser_1958, title={Hydrogen →Deuterium Exchange Reaction in Fibrous Proteins. I}, volume={29}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1744648}, DOI={10.1063/1.1744648}, number={5}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Fraser, R. D. B. and MacRae, T. P.}, year={1958}, month=nov, pages={1024–1028} }