DOI: 10.1063/1.1744362. Paramagnetic Species Produced by γ Irradiation of Organic Compounds

Paramagnetic Species Produced by γ Irradiation of Organic Compounds

10.1063/1.1744362

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

Some alkanes, olefins, alcohols, ethers, and a few other organic compounds have been irradiated with Co60 γ rays at low temperatures. The frozen irradiated samples have been examined for paramagnetic resonance, and the observed spectra in several cases have been identified with specific radicals. The methyl, ethyl, and allyl radicals are among those identified. The results in each case have been considered in relation to the present knowledge of the radiation chemistry of the compound. The mode of radical formation in many cases appears to be quite specific. Thus, in normal alkanes the major process for radical formation is by loss of a specific H atom. Hyperconjugation is used to interpret the resonance spectra.

Bibliography

Smaller, B., & Matheson, M. S. (1958). Paramagnetic Species Produced by Î³ Irradiation of Organic Compounds. The Journal of Chemical Physics, 28(6), 1169â1178.

Authors 2

B. Smaller (first)
M. S. Matheson (additional)

References 33 Referenced 193

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{'key': '2024020817541765300_r2'}
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Dates

Type	When
Created	20 years, 7 months ago (Jan. 5, 2005, 9:04 p.m.)
Deposited	1 year, 6 months ago (Feb. 8, 2024, 1:40 p.m.)
Indexed	1 month, 3 weeks ago (July 2, 2025, 11:39 a.m.)
Issued	67 years, 2 months ago (June 1, 1958)
Published	67 years, 2 months ago (June 1, 1958)
Published Print	67 years, 2 months ago (June 1, 1958)

Funders 0

None

BibTeX

@article{Smaller_1958, title={Paramagnetic Species Produced by γ Irradiation of Organic Compounds}, volume={28}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1744362}, DOI={10.1063/1.1744362}, number={6}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Smaller, B. and Matheson, M. S.}, year={1958}, month=jun, pages={1169–1178} }

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