DOI: 10.1063/1.1743945. Dissociation of CO+ and CO++ Ions by Collision with Neutral Molecules

Dissociation of CO+ and CO++ Ions by Collision with Neutral Molecules

10.1063/1.1743945

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The dissociations of CO+ and CO++ ions by ion-molecule collision have been investigated with a mass spectrometer. CO+ dissociates into C+ and O, or C and O+, depending upon the energy of the parent ion. The predominant ion resulting from dissociation of CO++ is C+ suggesting a charge-exchange dissociation reaction. This is supported by the observation that neutral molecules having high ionization potentials such as He and Ne do not produce dissociation in CO++. Energy for the dissociation of CO++ is derived from the electronic energy of the molecular ion rather than from kinetic energy.

Bibliography

Melton, C. E., & Wells, G. F. (1957). Dissociation of CO+ and CO++ Ions by Collision with Neutral Molecules. The Journal of Chemical Physics, 27(5), 1132â1141.

Authors 2

C. E. Melton (first)
G. F. Wells (additional)

References 24 Referenced 36

{'key': '2024020817405619500_r1', 'first-page': '317', 'volume': '19', 'year': '1920', 'journal-title': 'Proc. Cambridge Phil. Soc.'} / Proc. Cambridge Phil. Soc. (1920)
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10.6028/jres.043.006 / J. Research Natl. Bur. Standards (1949)
10.1063/1.1743290 / J. Chem. Phys. (1957)
10.1063/1.1743346 / J. Chem. Phys. (1957)
{'key': '2024020817405619500_r8'}
10.1073/pnas.38.8.667 / Proc. Natl. Acad. Sci. U.S. (1952)
{'key': '2024020817405619500_r10'}
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Dates

Type	When
Created	20 years, 7 months ago (Jan. 5, 2005, 8:54 p.m.)
Deposited	1 year, 6 months ago (Feb. 8, 2024, 1:33 p.m.)
Indexed	1 month, 2 weeks ago (July 2, 2025, 10:55 a.m.)
Issued	67 years, 9 months ago (Nov. 1, 1957)
Published	67 years, 9 months ago (Nov. 1, 1957)
Published Print	67 years, 9 months ago (Nov. 1, 1957)

Funders 0

None

BibTeX

@article{Melton_1957, title={Dissociation of CO+ and CO++ Ions by Collision with Neutral Molecules}, volume={27}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1743945}, DOI={10.1063/1.1743945}, number={5}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Melton, C. E. and Wells, G. F.}, year={1957}, month=nov, pages={1132–1141} }

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