DOI: 10.1063/1.1743761. Heterophase Fluctuations near the Freezing Point

Heterophase Fluctuations near the Freezing Point

10.1063/1.1743761

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

Numerical calculations of the magnitude of the effects caused by heterophase fluctuations predicted by Frenkel to occur near a first-order phase change are presented for o-cresol and benzene near their freezing point. The magnitude of the effect depends inversely on the number of degrees that the temperature is above the freezing point, the solid-liquid surface energy, and a parameter g0 that is related to the size of the regions in which pretransition phase changes occur. Appropriate values of the parameters in the theory are discussed and compared with experimental information where possible.

Bibliography

Lukasik, S. J. (1957). Heterophase Fluctuations near the Freezing Point. The Journal of Chemical Physics, 27(2), 523â527.

Authors 1

S. J. Lukasik (first)

References 34 Referenced 4

10.1103/PhysRev.31.174 / Phys. Rev. (1928)
10.1103/PhysRev.32.153 / Phys. Rev. (1928)
10.1103/PhysRev.35.726 / Phys. Rev. (1930)
10.1103/PhysRev.37.9 / Phys. Rev. (1931)
10.1103/PhysRev.30.232 / Phys. Rev. (1927)
10.1103/PhysRev.31.1 / Phys. Rev. (1928)
10.1103/PhysRev.31.10 / Phys. Rev. (1928)
10.1017/S0305004100011191 / Proc. Cambridge Phil. Soc. (1927)
10.1063/1.1749933 / J. Chem. Phys. (1937)
10.1063/1.1749934 / J. Chem. Phys. (1937)
10.1063/1.1750208 / J. Chem. Phys. (1938)
10.1063/1.1750194 / J. Chem. Phys. (1938)
10.1063/1.1750360 / J. Chem. Phys. (1939)
10.1063/1.1750361 / J. Chem. Phys. (1939)
10.1063/1.1750964 / J. Chem. Phys. (1941)
10.1063/1.1750822 / J. Chem. Phys. (1941)
10.1063/1.1750413 / J. Chem. Phys. (1939)
10.1063/1.1750484 / J. Chem. Phys. (1939)
10.1063/1.1750444 / J. Chem. Phys. (1939)
10.1063/1.1750346 / J. Chem. Phys. (1939)
{'key': '2024020817384321300_r6'}
10.1063/1.1746505 / J. Chem. Phys. (1947)
10.1021/j150483a005 / J. Phys. Colloid Chem. (1950)
{'key': '2024020817384321300_r8'}
{'key': '2024020817384321300_r9', 'first-page': '58', 'volume': '12', 'year': '1937', 'journal-title': 'Physik. Z. Sowjetunion'} / Physik. Z. Sowjetunion (1937)
{'key': '2024020817384321300_r10', 'first-page': '292', 'volume': '34', 'year': '1938', 'journal-title': 'Trans. Faraday Soc.'} / Trans. Faraday Soc. (1938)
10.1103/PhysRev.93.1161 / Phys. Rev. (1954)
10.1080/14786444108561378 / Phil. Mag. (1951)
{'key': '2024020817384321300_r13', 'first-page': '204', 'volume': '27', 'year': '1955', 'journal-title': 'J. Acoust. Soc. Am.'} / J. Acoust. Soc. Am. (1955)
10.1063/1.1742613 / J. Chem. Phys. (1956)
{'key': '2024020817384321300_r14'}
10.1103/PhysRev.54.916 / Phys. Rev. (1938)
{'key': '2024020817384321300_r15a'}
10.1063/1.1699435 / J. Appl. Phys. (1950)

Dates

Type	When
Created	20 years, 7 months ago (Jan. 5, 2005, 8:54 p.m.)
Deposited	1 year, 6 months ago (Feb. 8, 2024, 1:32 p.m.)
Indexed	1 year, 6 months ago (Feb. 9, 2024, 7:43 a.m.)
Issued	68 years ago (Aug. 1, 1957)
Published	68 years ago (Aug. 1, 1957)
Published Print	68 years ago (Aug. 1, 1957)

Funders 0

None

BibTeX

@article{Lukasik_1957, title={Heterophase Fluctuations near the Freezing Point}, volume={27}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1743761}, DOI={10.1063/1.1743761}, number={2}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Lukasik, S. J.}, year={1957}, month=aug, pages={523–527} }

JSON

{
  "indexed": {
    "date-parts": [
      [
        2024,
        2,
        9
      ]
    ],
    "date-time": "2024-02-09T12:43:50Z",
    "timestamp": 1707482630543
  },
  "reference-count": 34,
  "publisher": "AIP Publishing",
  "issue": "2",
  "content-domain": {
    "domain": [
      "pubs.aip.org"
    ],
    "crossmark-restriction": true
  },
  "published-print": {
    "date-parts": [
      [
        1957,
        8,
        1
      ]
    ]
  },
  "abstract": "<jats:p>Numerical calculations of the magnitude of the effects caused by heterophase fluctuations predicted by Frenkel to occur near a first-order phase change are presented for o-cresol and benzene near their freezing point. The magnitude of the effect depends inversely on the number of degrees that the temperature is above the freezing point, the solid-liquid surface energy, and a parameter g0 that is related to the size of the regions in which pretransition phase changes occur. Appropriate values of the parameters in the theory are discussed and compared with experimental information where possible.</jats:p>",
  "DOI": "10.1063/1.1743761",
  "type": "journal-article",
  "created": {
    "date-parts": [
      [
        2005,
        1,
        6
      ]
    ],
    "date-time": "2005-01-06T01:54:39Z",
    "timestamp": 1104976479000
  },
  "page": "523-527",
  "update-policy": "http://dx.doi.org/10.1063/aip-crossmark-policy-page",
  "source": "Crossref",
  "is-referenced-by-count": 4,
  "title": "Heterophase Fluctuations near the Freezing Point",
  "prefix": "10.1063",
  "volume": "27",
  "author": [
    {
      "given": "S. J.",
      "family": "Lukasik",
      "sequence": "first",
      "affiliation": [
        {
          "name": "Acoustics Laboratory, Massachusetts Institute of Technology, Cambridge, Massachusetts"
        }
      ]
    }
  ],
  "member": "317",
  "reference": [
    {
      "key": "2024020817384321300_r1",
      "doi-asserted-by": "crossref",
      "first-page": "174",
      "DOI": "10.1103/PhysRev.31.174",
      "volume": "31",
      "year": "1928",
      "journal-title": "Phys. Rev."
    },
    {
      "key": "2024020817384321300_r1a",
      "doi-asserted-by": "crossref",
      "first-page": "153",
      "DOI": "10.1103/PhysRev.32.153",
      "volume": "32",
      "year": "1928",
      "journal-title": "Phys. Rev."
    },
    {
      "key": "2024020817384321300_r1b",
      "doi-asserted-by": "crossref",
      "first-page": "726",
      "DOI": "10.1103/PhysRev.35.726",
      "volume": "35",
      "year": "1930",
      "journal-title": "Phys. Rev."
    },
    {
      "key": "2024020817384321300_r1c",
      "doi-asserted-by": "crossref",
      "first-page": "9",
      "DOI": "10.1103/PhysRev.37.9",
      "volume": "37",
      "year": "1931",
      "journal-title": "Phys. Rev."
    },
    {
      "key": "2024020817384321300_r1d",
      "doi-asserted-by": "crossref",
      "first-page": "232",
      "DOI": "10.1103/PhysRev.30.232",
      "volume": "30",
      "year": "1927",
      "journal-title": "Phys. Rev."
    },
    {
      "key": "2024020817384321300_r1e",
      "doi-asserted-by": "crossref",
      "first-page": "1",
      "DOI": "10.1103/PhysRev.31.1",
      "volume": "31",
      "year": "1928",
      "journal-title": "Phys. Rev."
    },
    {
      "key": "2024020817384321300_r1f",
      "doi-asserted-by": "crossref",
      "first-page": "10",
      "DOI": "10.1103/PhysRev.31.10",
      "volume": "31",
      "year": "1928",
      "journal-title": "Phys. Rev."
    },
    {
      "key": "2024020817384321300_r2",
      "doi-asserted-by": "crossref",
      "first-page": "685",
      "DOI": "10.1017/S0305004100011191",
      "volume": "23",
      "year": "1927",
      "journal-title": "Proc. Cambridge Phil. Soc."
    },
    {
      "key": "2024020817384321300_r3",
      "doi-asserted-by": "crossref",
      "first-page": "67",
      "DOI": "10.1063/1.1749933",
      "volume": "5",
      "year": "1937",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020817384321300_r3a",
      "doi-asserted-by": "crossref",
      "first-page": "74",
      "DOI": "10.1063/1.1749934",
      "volume": "5",
      "year": "1937",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020817384321300_r3b",
      "doi-asserted-by": "crossref",
      "first-page": "87",
      "DOI": "10.1063/1.1750208",
      "volume": "6",
      "year": "1938",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020817384321300_r3c",
      "doi-asserted-by": "crossref",
      "first-page": "101",
      "DOI": "10.1063/1.1750194",
      "volume": "6",
      "year": "1938",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020817384321300_r3d",
      "doi-asserted-by": "crossref",
      "first-page": "1019",
      "DOI": "10.1063/1.1750360",
      "volume": "7",
      "year": "1939",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020817384321300_r3e",
      "doi-asserted-by": "crossref",
      "first-page": "1025",
      "DOI": "10.1063/1.1750361",
      "volume": "7",
      "year": "1939",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020817384321300_r3f",
      "doi-asserted-by": "crossref",
      "first-page": "626",
      "DOI": "10.1063/1.1750964",
      "volume": "9",
      "year": "1941",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020817384321300_r3g",
      "doi-asserted-by": "crossref",
      "first-page": "2",
      "DOI": "10.1063/1.1750822",
      "volume": "9",
      "year": "1941",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020817384321300_r4",
      "doi-asserted-by": "crossref",
      "first-page": "200",
      "DOI": "10.1063/1.1750413",
      "volume": "7",
      "year": "1939",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020817384321300_r4a",
      "doi-asserted-by": "crossref",
      "first-page": "538",
      "DOI": "10.1063/1.1750484",
      "volume": "7",
      "year": "1939",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020817384321300_r5",
      "doi-asserted-by": "crossref",
      "first-page": "324",
      "DOI": "10.1063/1.1750444",
      "volume": "7",
      "year": "1939",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020817384321300_r5a",
      "doi-asserted-by": "crossref",
      "first-page": "927",
      "DOI": "10.1063/1.1750346",
      "volume": "7",
      "year": "1939",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020817384321300_r6"
    },
    {
      "key": "2024020817384321300_r7",
      "doi-asserted-by": "crossref",
      "first-page": "314",
      "DOI": "10.1063/1.1746505",
      "volume": "15",
      "year": "1947",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020817384321300_r7a",
      "doi-asserted-by": "crossref",
      "first-page": "1293",
      "DOI": "10.1021/j150483a005",
      "volume": "54",
      "year": "1950",
      "journal-title": "J. Phys. Colloid Chem."
    },
    {
      "key": "2024020817384321300_r8"
    },
    {
      "key": "2024020817384321300_r9",
      "first-page": "58",
      "volume": "12",
      "year": "1937",
      "journal-title": "Physik. Z. Sowjetunion"
    },
    {
      "key": "2024020817384321300_r10",
      "first-page": "292",
      "volume": "34",
      "year": "1938",
      "journal-title": "Trans. Faraday Soc."
    },
    {
      "key": "2024020817384321300_r11",
      "doi-asserted-by": "crossref",
      "first-page": "1161",
      "DOI": "10.1103/PhysRev.93.1161",
      "volume": "93",
      "year": "1954",
      "journal-title": "Phys. Rev."
    },
    {
      "key": "2024020817384321300_r12",
      "doi-asserted-by": "crossref",
      "first-page": "1209",
      "DOI": "10.1080/14786444108561378",
      "volume": "42",
      "year": "1951",
      "journal-title": "Phil. Mag."
    },
    {
      "key": "2024020817384321300_r13",
      "first-page": "204",
      "volume": "27",
      "year": "1955",
      "journal-title": "J. Acoust. Soc. Am."
    },
    {
      "key": "2024020817384321300_r13a",
      "doi-asserted-by": "crossref",
      "first-page": "803",
      "DOI": "10.1063/1.1742613",
      "volume": "24",
      "year": "1956",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020817384321300_r14"
    },
    {
      "key": "2024020817384321300_r15",
      "doi-asserted-by": "crossref",
      "first-page": "916",
      "DOI": "10.1103/PhysRev.54.916",
      "volume": "54",
      "year": "1938",
      "journal-title": "Phys. Rev."
    },
    {
      "key": "2024020817384321300_r15a"
    },
    {
      "key": "2024020817384321300_r16",
      "doi-asserted-by": "crossref",
      "first-page": "1022",
      "DOI": "10.1063/1.1699435",
      "volume": "21",
      "year": "1950",
      "journal-title": "J. Appl. Phys."
    }
  ],
  "container-title": "The Journal of Chemical Physics",
  "original-title": [],
  "language": "en",
  "link": [
    {
      "URL": "https://pubs.aip.org/aip/jcp/article-pdf/27/2/523/18812821/523_1_online.pdf",
      "content-type": "application/pdf",
      "content-version": "vor",
      "intended-application": "syndication"
    },
    {
      "URL": "https://pubs.aip.org/aip/jcp/article-pdf/27/2/523/18812821/523_1_online.pdf",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "similarity-checking"
    }
  ],
  "deposited": {
    "date-parts": [
      [
        2024,
        2,
        8
      ]
    ],
    "date-time": "2024-02-08T18:32:02Z",
    "timestamp": 1707417122000
  },
  "score": 1,
  "resource": {
    "primary": {
      "URL": "https://pubs.aip.org/jcp/article/27/2/523/77464/Heterophase-Fluctuations-near-the-Freezing-Point"
    }
  },
  "subtitle": [],
  "short-title": [],
  "issued": {
    "date-parts": [
      [
        1957,
        8,
        1
      ]
    ]
  },
  "references-count": 34,
  "journal-issue": {
    "issue": "2",
    "published-print": {
      "date-parts": [
        [
          1957,
          8,
          1
        ]
      ]
    }
  },
  "URL": "http://dx.doi.org/10.1063/1.1743761",
  "relation": {},
  "ISSN": [
    "0021-9606",
    "1089-7690"
  ],
  "subject": [],
  "published-other": {
    "date-parts": [
      [
        1957,
        8
      ]
    ]
  },
  "published": {
    "date-parts": [
      [
        1957,
        8,
        1
      ]
    ]
  }
}