DOI: 10.1063/1.1743252. Theory of Internal Over-All Rotational Interactions. IV. Stark Effect in Nonrigid Internal Rotors

Theory of Internal Over-All Rotational Interactions. IV. Stark Effect in Nonrigid Internal Rotors

10.1063/1.1743252

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

When a uniform electric field is applied to a nonrigid internal rotor, the ``Stark pattern'' of the energy levels is dependent upon the torsional motion. This dependence enters as a centrifugal distortion interaction and by means of the so-called ``repulsive effect'' of the potential barrier to internal rotation. These effects are small but observable and require that appropriate corrections be made in order to obtain an accurate and meaningful dipole moment from Stark effect measurements. The theory of the Stark effect in vibrating internal rotors has been formulated in this article with particular emphasis on its application to a molecule of C3v symmetry such as CH3SiH3. Krongelb and Strandberg have observed this effect in CH3SiH3.

Bibliography

Kivelson, D. (1957). Theory of Internal Over-All Rotational Interactions. IV. Stark Effect in Nonrigid Internal Rotors. The Journal of Chemical Physics, 26(1), 215â216.

Authors 1

Daniel Kivelson (first)

References 8 Referenced 10

10.1063/1.1740729 / J. Chem. Phys. (1955)
{'key': '2024020817051593000_r2'}
10.1063/1.1740730 / J. Chem. Phys. (1955)
{'key': '2024020817051593000_r4'}
10.1063/1.1739886 / J. Chem. Phys. (1954)
10.1063/1.1699170 / J. Chem. Phys. (1953)
10.1063/1.1723778 / J. Chem. Phys. (1943)
{'key': '2024020817051593000_r8'}

Dates

Type	When
Created	20 years, 7 months ago (Jan. 5, 2005, 8:40 p.m.)
Deposited	1 year, 6 months ago (Feb. 8, 2024, 12:57 p.m.)
Indexed	1 year, 6 months ago (Feb. 8, 2024, 1:10 p.m.)
Issued	68 years, 7 months ago (Jan. 1, 1957)
Published	68 years, 7 months ago (Jan. 1, 1957)
Published Print	68 years, 7 months ago (Jan. 1, 1957)

Funders 0

None

BibTeX

@article{Kivelson_1957, title={Theory of Internal Over-All Rotational Interactions. IV. Stark Effect in Nonrigid Internal Rotors}, volume={26}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1743252}, DOI={10.1063/1.1743252}, number={1}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Kivelson, Daniel}, year={1957}, month=jan, pages={215–216} }

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