DOI: 10.1063/1.1742955. Evaluation of Molecular Quadrupole Moments from Microwave Spectral Line Breadths. I. Theoretical

Evaluation of Molecular Quadrupole Moments from Microwave Spectral Line Breadths. I. Theoretical

10.1063/1.1742955

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The breadths of microwave spectral lines in gas mixtures may arise from several different interactions. It is shown that when the radiating molecule is the linear molecule OCS, polarizability interactions predominate, but when the radiating molecule is NH3 undergoing inversion, quadrupole moment interactions predominate. Consequently, NH3 is a particularly suitable molecule to use as a ``probe'' to measure quadrupole moments of other molecules. An improved theoretical analysis leads to a revision of previously published molecular quadrupole moments.

Bibliography

Smith, W. V. (1956). Evaluation of Molecular Quadrupole Moments from Microwave Spectral Line Breadths. I. Theoretical. The Journal of Chemical Physics, 25(3), 510â515.

Authors 1

William V. Smith (first)

References 12 Referenced 53

10.1103/PhysRev.79.132 / Phys. Rev. (1950)
{'key': '2024020816553667000_r2', 'first-page': '451', 'volume': '82', 'year': '1951', 'journal-title': 'Phys. Rev.'} / Phys. Rev. (1951)
10.1103/RevModPhys.17.227 / Revs. Modern Phys. (1945)
10.1103/PhysRev.76.647 / Phys. Rev. (1949)
{'key': '2024020816553667000_r5'}
10.1063/1.1741974 / J. Chem. Phys. (1955)
{'key': '2024020816553667000_r7'}
10.1103/PhysRev.80.511 / Phys. Rev. (1950)
{'key': '2024020816553667000_r9'}
{'key': '2024020816553667000_r10'}
{'key': '2024020816553667000_r11'}
{'key': '2024020816553667000_r11a'}

Dates

Type	When
Created	20 years, 7 months ago (Jan. 5, 2005, 8:24 p.m.)
Deposited	1 year, 6 months ago (Feb. 8, 2024, 12:54 p.m.)
Indexed	1 year, 6 months ago (Feb. 9, 2024, 6:06 p.m.)
Issued	69 years ago (Sept. 1, 1956)
Published	69 years ago (Sept. 1, 1956)
Published Print	69 years ago (Sept. 1, 1956)

Funders 0

None

BibTeX

@article{Smith_1956, title={Evaluation of Molecular Quadrupole Moments from Microwave Spectral Line Breadths. I. Theoretical}, volume={25}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1742955}, DOI={10.1063/1.1742955}, number={3}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Smith, William V.}, year={1956}, month=sep, pages={510–515} }

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