DOI: 10.1063/1.1742877. Rate of Electron Exchange between Cuprous and Cupric Ions in Hydrochloric Acid Solutions by Nuclear Magnetic Resonance

Rate of Electron Exchange between Cuprous and Cupric Ions in Hydrochloric Acid Solutions by Nuclear Magnetic Resonance

10.1063/1.1742877

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

A determination of the Cu63 nuclear resonance line width in concentrated hydrochloric acid solutions containing both cuprous and cupric chloride leads to an evaluation of the bimolecular rate constant k for the electron exchange process Cu+++Cu+→+Cu++Cu++.The experimentally determined value for k is k = 0.5×108 liter/mole-second.

Bibliography

McConnell, H. M., & Weaver, H. E. (1956). Rate of Electron Exchange between Cuprous and Cupric Ions in Hydrochloric Acid Solutions by Nuclear Magnetic Resonance. The Journal of Chemical Physics, 25(2), 307â311.

Authors 2

H. M. McConnell (first)
H. E. Weaver (additional)

References 9 Referenced 61

10.1021/cr50001a004 / Chem. Revs. (1955)
10.1021/ja01163a099 / J. Am. Chem. Soc. (1950)
10.1103/PhysRev.73.679 / Phys. Rev. (1948)
10.1103/PhysRev.74.1184 / Phys. Rev. (1948)
10.1103/PhysRev.70.460 / Phys. Rev. (1946)
10.1119/1.1932628 / Am. J. Phys. (1950)
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Dates

Type	When
Created	20 years, 7 months ago (Jan. 5, 2005, 8:24 p.m.)
Deposited	1 year, 6 months ago (Feb. 8, 2024, 12:51 p.m.)
Indexed	1 year, 6 months ago (Feb. 8, 2024, 6:03 p.m.)
Issued	69 years, 1 month ago (Aug. 1, 1956)
Published	69 years, 1 month ago (Aug. 1, 1956)
Published Print	69 years, 1 month ago (Aug. 1, 1956)

Funders 0

None

BibTeX

@article{McConnell_1956, title={Rate of Electron Exchange between Cuprous and Cupric Ions in Hydrochloric Acid Solutions by Nuclear Magnetic Resonance}, volume={25}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1742877}, DOI={10.1063/1.1742877}, number={2}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={McConnell, H. M. and Weaver, H. E.}, year={1956}, month=aug, pages={307–311} }

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