DOI: 10.1063/1.1742808. Curved Fluid Interfaces. I. The Generalized Gibbs-Kelvin Equation

Curved Fluid Interfaces. I. The Generalized Gibbs-Kelvin Equation

10.1063/1.1742808

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The properties of curved fluid interfaces in the presence of external fields are examined from the molecular point of view and are shown to imply a generalized Gibbs-Kelvin equation. These results are then related to Gibbs' phenomenological treatment and thus provide expressions for the relevant thermodynamic parameters in terms of the detailed properties of the transition zone. The formulation leads to an asymptotic estimate of the free energy and to corrections for the Laplace equation determining the shapes of interfaces.

Bibliography

Buff, F. P. (1956). Curved Fluid Interfaces. I. The Generalized Gibbs-Kelvin Equation. The Journal of Chemical Physics, 25(1), 146â153.

Authors 1

Frank P. Buff (first)

References 9 Referenced 78

10.1063/1.1742005 / J. Chem. Phys. (1955)
{'key': '2024020816550808300_r2'}
10.1063/1.1747782 / J. Chem. Phys. (1950)
{'key': '2024020816550808300_r4'}
{'key': '2024020816550808300_r5'}
{'key': '2024020816550808300_r6'}
10.1063/1.1748352 / J. Chem. Phys. (1951)
10.1063/1.1747248 / J. Chem. Phys. (1949)
{'key': '2024020816550808300_r9'}

Dates

Type	When
Created	20 years, 8 months ago (Jan. 5, 2005, 8:24 p.m.)
Deposited	1 year, 6 months ago (Feb. 8, 2024, 12:53 p.m.)
Indexed	2 days, 20 hours ago (Sept. 4, 2025, 9:48 a.m.)
Issued	69 years, 2 months ago (July 1, 1956)
Published	69 years, 2 months ago (July 1, 1956)
Published Print	69 years, 2 months ago (July 1, 1956)

Funders 0

None

BibTeX

@article{Buff_1956, title={Curved Fluid Interfaces. I. The Generalized Gibbs-Kelvin Equation}, volume={25}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1742808}, DOI={10.1063/1.1742808}, number={1}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Buff, Frank P.}, year={1956}, month=jul, pages={146–153} }

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