DOI: 10.1063/1.1740675. Infrared Spectra and Structure of the Crystalline Sodium Acetate Complexes of U(VI), Np(VI), Pu(VI), and Am(VI). A Comparison of Metal-Oxygen Bond Distance and Bond Force Constant in this Series

Infrared Spectra and Structure of the Crystalline Sodium Acetate Complexes of U(VI), Np(VI), Pu(VI), and Am(VI). A Comparison of Metal-Oxygen Bond Distance and Bond Force Constant in this Series

10.1063/1.1740675

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

Infrared spectra of solid NaXO2(Ac)3, with X=U, Np, Pu, and Am, have been observed. From the symmetric and asymmetric stretching frequencies of the O–X–O groups, approximate X–O force constants have been calculated and were found to decrease in the order kU—O&gt;kNp—O&gt;kPu—O&gt; kAm—O, the respective values being about 0.705, 0.698, 0.675, and 0.612 megadyne/cm. From the cell constants for NaXO2(Ac)3 it is apparent that the X–O bond distance decreases in the same order—RU—O&gt;RNp—O&gt;RPu—O&gt;RAm—O. Thus, a decrease in bond distance appears to be accompanied by a decrease in force constant, probably because the bond, though shortened by contraction of the electron shells of the metal, is weakened by interaction with the extra valence shell electrons.

Bibliography

Jones, L. H. (1955). Infrared Spectra and Structure of the Crystalline Sodium Acetate Complexes of U(VI), Np(VI), Pu(VI), and Am(VI). A Comparison of Metal-Oxygen Bond Distance and Bond Force Constant in this Series. The Journal of Chemical Physics, 23(11), 2105â2107.

Authors 1

Llewellyn H. Jones (first)

References 6 Referenced 89

10.1063/1.1698941 / J. Chem. Phys. (1953)
10.1103/PhysRev.73.1104 / Phys. Rev. (1948)
{'key': '2024020816313532400_r2a'}
{'key': '2024020816313532400_r3'}
10.1063/1.1739921 / J. Chem. Phys. (1954)
10.1039/tf9413700293 / Trans. Faraday Soc. (1941)

Dates

Type	When
Created	20 years, 4 months ago (April 22, 2005, 1:26 p.m.)
Deposited	1 year, 6 months ago (Feb. 8, 2024, 12:36 p.m.)
Indexed	1 month, 3 weeks ago (July 14, 2025, 11:21 p.m.)
Issued	69 years, 10 months ago (Nov. 1, 1955)
Published	69 years, 10 months ago (Nov. 1, 1955)
Published Print	69 years, 10 months ago (Nov. 1, 1955)

Funders 0

None

BibTeX

@article{Jones_1955, title={Infrared Spectra and Structure of the Crystalline Sodium Acetate Complexes of U(VI), Np(VI), Pu(VI), and Am(VI). A Comparison of Metal-Oxygen Bond Distance and Bond Force Constant in this Series}, volume={23}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1740675}, DOI={10.1063/1.1740675}, number={11}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Jones, Llewellyn H.}, year={1955}, month=nov, pages={2105–2107} }

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