Abstract
The multiple origin method has been utilized for the selection of initial coordinates for the description of the normal vibrations of N-dimethylaminodiborane. Symmetry considerations were then used in order to obtain symmetry coordinates from these MOM coordinates, and, under the assumption of a diagonal potential function, these coordinates were assigned to vibrational frequencies which have been recently reported by Mann. The valence force constants for the methyl-N-methyl framework vibrations were then calculated and the results compared with similar constants obtained from the dimethylamine molecule.
References
10
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Dates
Type | When |
---|---|
Created | 20 years, 4 months ago (April 22, 2005, 1:26 p.m.) |
Deposited | 1 year, 6 months ago (Feb. 8, 2024, 12:08 p.m.) |
Indexed | 1 year, 6 months ago (Feb. 8, 2024, 1:05 p.m.) |
Issued | 70 years, 7 months ago (Jan. 1, 1955) |
Published | 70 years, 7 months ago (Jan. 1, 1955) |
Published Print | 70 years, 7 months ago (Jan. 1, 1955) |
@article{Breene_1955, title={The Normal Coordinates of N-Dimethylaminodiborane}, volume={23}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1740572}, DOI={10.1063/1.1740572}, number={1}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Breene, R. G.}, year={1955}, month=jan, pages={97–102} }