Abstract
The 000—101 rotational transitions of several isotopic species of methyl mercaptan have been observed. This has permitted a complete determination of the structural parameters of this molecule. The torsional energy levels of C12H3S32H and C12D3S32H have been approximately determined by relative intensity measurements. A sinusoidal barrier height has been determined which gives torsional energy levels in agreement with the observed ones.
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Dates
Type | When |
---|---|
Created | 20 years, 4 months ago (April 22, 2005, 1:26 p.m.) |
Deposited | 1 year, 6 months ago (Feb. 8, 2024, 12:17 p.m.) |
Indexed | 1 month, 4 weeks ago (July 2, 2025, 4:10 p.m.) |
Issued | 70 years, 7 months ago (Jan. 1, 1955) |
Published | 70 years, 7 months ago (Jan. 1, 1955) |
Published Print | 70 years, 7 months ago (Jan. 1, 1955) |
@article{Solimene_1955, title={Structure and Barrier Height of Methyl Mercaptan from Microwave Data}, volume={23}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1740509}, DOI={10.1063/1.1740509}, number={1}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Solimene, N. and Dailey, B. P.}, year={1955}, month=jan, pages={124–129} }