DOI: 10.1063/1.1740465. Cation Distribution and <i>g</i> Factors of Certain Spinels Containing Ni++, Mn++, Co++, Al+++, Ga+++, and Fe+++

Cation Distribution and g Factors of Certain Spinels Containing Ni++, Mn++, Co++, Al+++, Ga+++, and Fe+++

10.1063/1.1740465

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

X-ray measurements on NiOAl2O3, MnOAl2O3, and CoOAl2O3 show that the Ni spinel is almost completely inverted, the Mn partially so, and the Co compound almost completely normal. This information combined with the magnetic susceptibility vs temperature data yields a g-value of approximately 4.0 for both tetrahedrally coordinated Ni++ and for octahedrally coordinated Co++. X-ray measurements indicate that the Ni++ ion also prefers the octahedral site in NiOGa2O3, NiOFe1.00Al1.00O3, and NiOFe0.25Al1.75O3.

Bibliography

Greenwald, S., Pickart, S. J., & Grannis, F. H. (1954). Cation Distribution and g Factors of Certain Spinels Containing Ni++, Mn++, Co++, Al+++, Ga+++, and Fe+++. The Journal of Chemical Physics, 22(9), 1597â1600.

Authors 3

Selma Greenwald (first)
Stanley J. Pickart (additional)
Frederick H. Grannis (additional)

References 19 Referenced 80

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{'issue': '9', 'key': '2024020815385955900_r2', 'volume': '23', 'year': '1927', 'journal-title': 'Univ. Arsskr.'} / Univ. Arsskr. (1927)
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Dates

Type	When
Created	20 years, 4 months ago (April 26, 2005, 10:08 a.m.)
Deposited	1 year, 6 months ago (Feb. 8, 2024, 11:56 a.m.)
Indexed	1 month, 4 weeks ago (July 8, 2025, 6:27 a.m.)
Issued	71 years ago (Sept. 1, 1954)
Published	71 years ago (Sept. 1, 1954)
Published Print	71 years ago (Sept. 1, 1954)

Funders 0

None

BibTeX

@article{Greenwald_1954, title={Cation Distribution and g Factors of Certain Spinels Containing Ni++, Mn++, Co++, Al+++, Ga+++, and Fe+++}, volume={22}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1740465}, DOI={10.1063/1.1740465}, number={9}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Greenwald, Selma and Pickart, Stanley J. and Grannis, Frederick H.}, year={1954}, month=sep, pages={1597–1600} }

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