DOI: 10.1063/1.1740150. Kinetics of the Fast Gas Phase Reaction between Ozone and Nitric Oxide

Kinetics of the Fast Gas Phase Reaction between Ozone and Nitric Oxide

10.1063/1.1740150

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The rate of reaction between ozone and nitric oxide was followed optically at —43 and —75°. The reaction appears to be elementary bimolecular NO+O3=NO2+O2and the rate constant is k=0.8×1012e−2500/RT cc mole−1sec−1. The pre-exponential factor for this reaction is compared with those of six other elementary gas phase reactions of the type X+Y=Z+W+···involving the oxides of nitrogen for which the energies of activation were higher. For this series of similar reactions the molecular complexity of the reactants is about constant (five or six atoms), and there appears to be no systematic difference in pre-exponential factor between the fast and the slow reactions.

Bibliography

Johnston, H. S., & Crosby, H. J. (1954). Kinetics of the Fast Gas Phase Reaction between Ozone and Nitric Oxide. The Journal of Chemical Physics, 22(4), 689â692.

Authors 2

Harold S. Johnston (first)
Harvey J. Crosby (additional)

References 8 Referenced 49

10.1063/1.1747264 / J. Chem. Phys. (1949)
10.1021/ja01147a015 / J. Am. Chem. Soc. (1951)
10.1021/ja01432a004 / J. Am. Chem. Soc. (1922)
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10.1063/1.1700281 / J. Chem. Phys. (1952)
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Dates

Type	When
Created	20 years, 4 months ago (April 26, 2005, 10:08 a.m.)
Deposited	1 year, 6 months ago (Feb. 8, 2024, 11:55 a.m.)
Indexed	2 months ago (June 23, 2025, 7:24 a.m.)
Issued	71 years, 4 months ago (April 1, 1954)
Published	71 years, 4 months ago (April 1, 1954)
Published Print	71 years, 4 months ago (April 1, 1954)

Funders 0

None

BibTeX

@article{Johnston_1954, title={Kinetics of the Fast Gas Phase Reaction between Ozone and Nitric Oxide}, volume={22}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1740150}, DOI={10.1063/1.1740150}, number={4}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Johnston, Harold S. and Crosby, Harvey J.}, year={1954}, month=apr, pages={689–692} }

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