Abstract
Nuclear magnetic resonance absorption in oriented polytetrafluoroethylene fibers has been investigated in the temperature range 170°–380°K. The sample, in the form of a parallel bundle of fibers, showed a marked dependence of line shape on the direction of the applied magnetic field over the temperature range studied, although the observed anisotropy was much greater above 285°K than below. Changes occurring in the linewidth and second moment at around 285°K indicate a rotational disorder transition in the crystalline regions of the polymer, and serve to illustrate the advantages of using oriented fibers in the NMR investigation of semicrystalline polymers.
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Dates
Type | When |
---|---|
Created | 20 years, 4 months ago (April 25, 2005, 1:03 p.m.) |
Deposited | 1 year, 7 months ago (Feb. 1, 2024, 2:29 p.m.) |
Indexed | 11 months, 2 weeks ago (Sept. 19, 2024, 11:02 a.m.) |
Issued | 64 years, 10 months ago (Nov. 1, 1960) |
Published | 64 years, 10 months ago (Nov. 1, 1960) |
Published Print | 64 years, 10 months ago (Nov. 1, 1960) |
@article{Hyndman_1960, title={NMR Absorption in Teflon Fibers}, volume={31}, ISSN={1089-7550}, url={http://dx.doi.org/10.1063/1.1735462}, DOI={10.1063/1.1735462}, number={11}, journal={Journal of Applied Physics}, publisher={AIP Publishing}, author={Hyndman, D. and Origlio, G. F.}, year={1960}, month=nov, pages={1849–1852} }