DOI: 10.1063/1.1734534. Raman Spectrum and Vibrational Assignment for Molten Thallous Nitrate

Raman Spectrum and Vibrational Assignment for Molten Thallous Nitrate

10.1063/1.1734534

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The Raman data for TlNO3 (mp 206°C) in the pure molten state are: 1036 (10, p), 1328 (3.3, dp), 1383 (3.9, dp), and 1637 (2.5) cm—1, and two relatively low frequencies, 708 (1.3) and 813 (1.7) cm—1. The results are examined in light of the vibrational assignments for D3h and C2v point group symmetries in solid-state nitrates, and for D3h symmetry for related nitrates in the molten state. An assignment of the Raman activity of molten TlNO3 based on retention of D3h symmetry is advanced; the appearance of the Raman ``forbidden'' frequencies (v2) and the loss of degeneracy (v3) are attributed to cationic environmental effects in this molten salt.

Bibliography

Janz, G. J., Kozlowski, T. R., & Wait, S. C. (1963). Raman Spectrum and Vibrational Assignment for Molten Thallous Nitrate. The Journal of Chemical Physics, 39(7), 1809â1812.

Authors 3

G. J. Janz (first)
T. R. Kozlowski (additional)
S. C. Wait (additional)

References 12 Referenced 18

10.1063/1.1731994 / J. Chem. Phys. (1961)
{'key': '2024020821504415800_r2', 'first-page': '341', 'volume': '8', 'year': '1934', 'journal-title': 'Indian J. Phys.'} / Indian J. Phys. (1934)
{'key': '2024020821504415800_r3', 'first-page': '261', 'volume': '17', 'year': '1949', 'journal-title': 'J. Chem. Phys.'} / J. Chem. Phys. (1949)
10.1366/000370261774427145 / J. Appl. Spectry. (1961)
10.1364/JOSA.43.000110 / J. Opt. Soc. Am. (1953)
{'key': '2024020821504415800_r6', 'first-page': '66', 'volume': '32', 'year': '1961', 'journal-title': 'Discussions Faraday Soc.'} / Discussions Faraday Soc. (1961)
10.1038/174644a0 / Nature (1954)
{'key': '2024020821504415800_r8'}
10.1366/000370259774614960 / J. Appl. Spectry. (1959)
10.1016/0022-2852(60)90071-0 / J. Mol. Spectry. (1960)
10.1016/S0371-1951(62)80139-8 / Speetrochim. Acta (1962)
{'key': '2024020821504415800_r12'}

Dates

Type	When
Created	20 years, 8 months ago (Jan. 5, 2005, 10:57 p.m.)
Deposited	1 year, 6 months ago (Feb. 8, 2024, 4:50 p.m.)
Indexed	1 year, 6 months ago (Feb. 9, 2024, 6:56 a.m.)
Issued	61 years, 11 months ago (Oct. 1, 1963)
Published	61 years, 11 months ago (Oct. 1, 1963)
Published Print	61 years, 11 months ago (Oct. 1, 1963)

Funders 0

None

BibTeX

@article{Janz_1963, title={Raman Spectrum and Vibrational Assignment for Molten Thallous Nitrate}, volume={39}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1734534}, DOI={10.1063/1.1734534}, number={7}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Janz, G. J. and Kozlowski, T. R. and Wait, S. C.}, year={1963}, month=oct, pages={1809–1812} }

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