DOI: 10.1063/1.1734353. Microwave Spectrum, Structure, and Dipole Moment of ``<i>Cis</i>''-N2F2

Microwave Spectrum, Structure, and Dipole Moment of ``Cis''-N2F2

10.1063/1.1734353

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The microwave spectra of the F14N14NF and F15N14NF isotopic forms of the ``active'' isomer of N2F2 are reported and from this the structure is derived as planar and cis with the following structural parameters: d(NN)=1.214±0.005 Å, d(NF)=1.384±0.01 Å, ∠FNN=114.5±0.5°. A dipole moment of 0.16±0.01 D has been evaluated from the rotational Stark effect. Transitions of the molecule in an excited vibrational state are reported. From relative intensity measurements of this state, a vibrational frequency of 300±35 cm-1 is estimated. A method is demonstrated enabling the ratio of nuclear spin statistical weights of two transitions to be determined from the growth rate of their intensities with increasing Stark modulation voltage.

Bibliography

Kuczkowski, R. L., & Wilson, E. B. (1963). Microwave Spectrum, Structure, and Dipole Moment of ``Cisââ-N2F2. The Journal of Chemical Physics, 39(4), 1030â1034.

Authors 2

Robert L. Kuczkowski (first)
E. Bright Wilson (additional)

References 30 Referenced 48

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Dates

Type	When
Created	20 years, 8 months ago (Jan. 5, 2005, 10:57 p.m.)
Deposited	1 year, 6 months ago (Feb. 8, 2024, 4:44 p.m.)
Indexed	1 year, 6 months ago (Feb. 11, 2024, 12:22 a.m.)
Issued	62 years ago (Aug. 15, 1963)
Published	62 years ago (Aug. 15, 1963)
Published Print	62 years ago (Aug. 15, 1963)

Funders 0

None

BibTeX

@article{Kuczkowski_1963, title={Microwave Spectrum, Structure, and Dipole Moment of ``Cis’’-N2F2}, volume={39}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1734353}, DOI={10.1063/1.1734353}, number={4}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Kuczkowski, Robert L. and Wilson, E. Bright}, year={1963}, month=aug, pages={1030–1034} }

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