DOI: 10.1063/1.1734205. Molecular Weight Distribution of Linear Polymers from Stress Relaxation in Polymer Melts

Molecular Weight Distribution of Linear Polymers from Stress Relaxation in Polymer Melts

10.1063/1.1734205

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The method of Menefee and Peticolas for obtaining the molecular weight distribution of linear polymers from stress relaxation after steady-state flow has been applied to data on melt samples: a linear polyethylene and polystyrene sample. The results offer considerable promise for a rapid estimation of the high molecular portion of the distribution curve. The method is based on a rather straightforward extension of the theory of Roase to bulk molten polymers. A discussion of the validity of this process is given in the light of recent developments.

Bibliography

Peticolas, W. L. (1963). Molecular Weight Distribution of Linear Polymers from Stress Relaxation in Polymer Melts. The Journal of Chemical Physics, 39(12), 3392â3400.

Authors 1

Warner L. Peticolas (first)

References 18 Referenced 18

10.1063/1.1699180 / J. Chem. Phys. (1953)
10.1063/1.1740133 / J. Chem. Phys. (1954)
10.1063/1.1701243 / J. Chem. Phys. (1961)
10.1063/1.1701244 / J. Chem. Phys. (1961)
10.1063/1.1732219 / J. Chem. Phys. (1961)
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10.1021/ie50508a019 / Ind. Eng. Chem. (1952)
10.1016/S0031-8914(52)80267-8 / Physica (1952)
{'key': '2024020822141546600_r12'}
{'key': '2024020822141546600_r13'}
10.1002/pol.1954.120147306 / J. Polymer Sci. (1954)
{'key': '2024020822141546600_r15'}
10.1002/pol.1959.1204013714 / J. Polymer Sci. (1959)
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{'key': '2024020822141546600_r18', 'first-page': '535', 'volume': '51', 'year': '1961', 'journal-title': 'J. Polymer Sci.'} / J. Polymer Sci. (1961)

Dates

Type	When
Created	20 years, 7 months ago (Jan. 5, 2005, 10:57 p.m.)
Deposited	1 year, 6 months ago (Feb. 8, 2024, 5:14 p.m.)
Indexed	1 year, 6 months ago (Feb. 8, 2024, 11:07 p.m.)
Issued	61 years, 8 months ago (Dec. 15, 1963)
Published	61 years, 8 months ago (Dec. 15, 1963)
Published Print	61 years, 8 months ago (Dec. 15, 1963)

Funders 0

None

BibTeX

@article{Peticolas_1963, title={Molecular Weight Distribution of Linear Polymers from Stress Relaxation in Polymer Melts}, volume={39}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1734205}, DOI={10.1063/1.1734205}, number={12}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Peticolas, Warner L.}, year={1963}, month=dec, pages={3392–3400} }

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