DOI: 10.1063/1.1734090. Mass-Spectrometric Investigation of the Oxidation of Molybdenum and Tungsten

Mass-Spectrometric Investigation of the Oxidation of Molybdenum and Tungsten

10.1063/1.1734090

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The oxidation of molybdenum and tungsten was investigated mass spectrometrically at temperatures between 1500° and 2600°K and oxygen pressures between 10—4 and 10—2 Torr. The principal products of oxidation were found to be the gaseous dioxide and trioxide, MO2(g) and MO3(g) (M=Mo or W). The trioxide is the more important species at low temperatures; the dioxide is the dominant product at high temperatures. Small amounts of polymeric oxides, (MO3)2(g) and (MO3)3(g) were formed at the lowest temperatures and highest oxygen pressures. The gaseous oxidation products are not in equilibrium with a solid surface oxide.

Bibliography

Berkowitz-Mattuck, J. B., BÃ¼chler, A., Engelke, J. L., & Goldstein, S. N. (1963). Mass-Spectrometric Investigation of the Oxidation of Molybdenum and Tungsten. The Journal of Chemical Physics, 39(10), 2722â2730.

Authors 4

Joan B. Berkowitz-Mattuck (first)
Alfred Büchler (additional)
John L. Engelke (additional)
Steven N. Goldstein (additional)

References 31 Referenced 64

{'key': '2024020822122831500_r1', 'first-page': '628', 'volume': '175', 'year': '1948', 'journal-title': 'Trans. AIME'} / Trans. AIME (1948)
{'key': '2024020822122831500_r2', 'first-page': '280', 'volume': '212', 'year': '1960', 'journal-title': 'Trans. AIME'} / Trans. AIME (1960)
{'key': '2024020822122831500_r3', 'first-page': '1011', 'volume': '203', 'year': '1955', 'journal-title': 'Trans. AIME'} / Trans. AIME (1955)
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{'key': '2024020822122831500_r5'}
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{'key': '2024020822122831500_r10', 'first-page': '490', 'volume': '13', 'year': '1961', 'journal-title': 'J. Metals'} / J. Metals (1961)
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{'key': '2024020822122831500_r12'}
{'key': '2024020822122831500_r13'}
{'key': '2024020822122831500_r14', 'first-page': '85', 'volume': '28', 'year': '1957', 'journal-title': 'J. Chem. Phys.'} / J. Chem. Phys. (1957)
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{'key': '2024020822122831500_r30', 'first-page': '135', 'volume': '7', 'year': '1958', 'journal-title': 'Advan. Catalysis'} / Advan. Catalysis (1958)

Dates

Type	When
Created	20 years, 7 months ago (Jan. 5, 2005, 10:57 p.m.)
Deposited	1 year, 6 months ago (Feb. 8, 2024, 5:12 p.m.)
Indexed	1 year, 3 months ago (May 17, 2024, 12:53 p.m.)
Issued	61 years, 9 months ago (Nov. 15, 1963)
Published	61 years, 9 months ago (Nov. 15, 1963)
Published Print	61 years, 9 months ago (Nov. 15, 1963)

Funders 0

None

BibTeX

@article{Berkowitz_Mattuck_1963, title={Mass-Spectrometric Investigation of the Oxidation of Molybdenum and Tungsten}, volume={39}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1734090}, DOI={10.1063/1.1734090}, number={10}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Berkowitz-Mattuck, Joan B. and Büchler, Alfred and Engelke, John L. and Goldstein, Steven N.}, year={1963}, month=nov, pages={2722–2730} }

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