DOI: 10.1063/1.1734071. Conformal Ionic Mixtures

10.1063/1.1734071

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The excess free energy of mixing of molten reciprocal salt solutions (A+, B+, X—, Y—) has been calculated up to the second order by the perturbation method of Reiss, Katz, and Kleppa. The result is a power series containing integral powers of the ion fractions (concentrations). This demonstrates that mixtures of two salts of the same valence type cannot be considered as a mixture of a salt with a dielectric solvent. The first term in the series is proportional to the free-energy change for the reaction AX+BY→AY+BX and is the same as the theory of Flood, Fo/rland, and Grjotheim. The results of the symmetric approximation based upon the quasilattice model are consistent with the first term and one of the second-order terms. The remaining second-order terms are related to the excess free energy of mixing in the binary systems AX—AY, BX—BY, AX—BX, AY—BY and are of a form first suggested by Fo/rland. This theory, thus, gives a relatively rigorous justification to aspects of previous theories of reciprocal salt solutions which were based upon restrictive models and assumptions.

Bibliography

Blander, M., & Yosim, S. J. (1963). Conformal Ionic Mixtures. The Journal of Chemical Physics, 39(10), 2610â2616.

Authors 2

Milton Blander (first)
S. J. Yosim (additional)

References 19 Referenced 80

10.1063/1.1732285 / J. Chem. Phys. (1962)
{'key': '2024020821595560100_r2', 'first-page': '247', 'volume': 'A205', 'year': '1951', 'journal-title': 'Proc. Roy. Soc. (London)'} / Proc. Roy. Soc. (London) (1951)
10.1063/1.1732946 / J. Chem. Phys. (1962)
10.1002/zaac.19542760509 / Z. Anorg. Allgem. Chem. (1954)
10.1111/j.1749-6632.1960.tb42758.x / Ann. N.Y. Acad. Sci. (1960)
{'key': '2024020821595560100_r6'}
{'key': '2024020821595560100_r7'}
10.1111/j.1749-6632.1960.tb42753.x / Ann. N.Y. Acad. Sci. (1960)
{'key': '2024020821595560100_r9'}
{'key': '2024020821595560100_r10'}
{'key': '2024020821595560100_r11'}
{'key': '2024020821595560100_r12'}
{'key': '2024020821595560100_r13'}
10.1080/00268975900100031 / Mol. Phys. (1959)
{'key': '2024020821595560100_r15', 'first-page': '834', 'volume': '59', 'year': '1955', 'journal-title': 'Z. Elektrochem.'} / Z. Elektrochem. (1955)
10.1021/j150578a011 / J. Phys. Chem. (1959)
10.1063/1.1700968 / J. Chem. Phys. (1961)
{'key': '2024020821595560100_r18'}
{'issue': '4', 'key': '2024020821595560100_r19', 'volume': '2', 'year': '1957', 'journal-title': 'Norge Tek. Vitenskapsakad.'} / Norge Tek. Vitenskapsakad. (1957)

Dates

Type	When
Created	20 years, 7 months ago (Jan. 5, 2005, 10:57 p.m.)
Deposited	1 year, 6 months ago (Feb. 8, 2024, 5 p.m.)
Indexed	1 year, 3 months ago (May 14, 2024, 9:17 p.m.)
Issued	61 years, 9 months ago (Nov. 15, 1963)
Published	61 years, 9 months ago (Nov. 15, 1963)
Published Print	61 years, 9 months ago (Nov. 15, 1963)

Funders 0

None

BibTeX

@article{Blander_1963, title={Conformal Ionic Mixtures}, volume={39}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1734071}, DOI={10.1063/1.1734071}, number={10}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Blander, Milton and Yosim, S. J.}, year={1963}, month=nov, pages={2610–2616} }

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