DOI: 10.1063/1.1733796. Reinvestigation of Some Absolute Rate Measurements of O-Atom Reactions with Olefins

Reinvestigation of Some Absolute Rate Measurements of O-Atom Reactions with Olefins

10.1063/1.1733796

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The rate constants, activation energies, and pre-exponential factors for the primary reactions of atomic oxygen with ethylene, butene-1, iso-butene, and cis-butene-2 have been determined. The measurements were carried out in a fast-flow system in which O atoms were produced by electrical discharge. Possible sources of error such as the presence of O2 and the effect of surface reactions are shown to be unimportant. The results show a systematic deviation from those of previous studies in which a photolysis technique was used to obtain relative rate data. The possibility of secondary attack on the olefins is discussed and considered an unlikely cause for the observed discrepancies.

Bibliography

Elias, L. (1963). Reinvestigation of Some Absolute Rate Measurements of O-Atom Reactions with Olefins. The Journal of Chemical Physics, 38(4), 989â995.

Authors 1

Lorne Elias (first)

References 12 Referenced 44

10.1063/1.1731334 / J. Chem. Phys. (1960)
10.1139/v60-231 / Can. J. Chem. (1960)
10.1063/1.1731292 / J. Chem. Phys. (1960)
10.1139/v58-185 / Can. J. Chem. (1958)
10.1063/1.1742312 / J. Chem. Phys. (1955)
10.1139/v59-073 / Can. J. Chem. (1959)
10.1063/1.1729874 / J. Chem. Phys. (1959)
10.1063/1.1743948 / J. Chem. Phys. (1957)
{'key': '2024020821265781600_r9'}
10.1063/1.1732028 / J. Chem. Phys. (1961)
{'key': '2024020821265781600_r11', 'first-page': '445', 'volume': 'A196', 'year': '1949', 'journal-title': 'Proc. Roy. Soc. (London)'} / Proc. Roy. Soc. (London) (1949)
{'key': '2024020821265781600_r11a', 'first-page': '181', 'volume': 'A202', 'year': '1950', 'journal-title': 'Proc. R. Soc. London, Ser. A'} / Proc. R. Soc. London, Ser. A (1950)

Dates

Type	When
Created	20 years, 7 months ago (Jan. 9, 2005, 1:59 a.m.)
Deposited	1 year, 6 months ago (Feb. 8, 2024, 4:27 p.m.)
Indexed	1 year, 6 months ago (Feb. 9, 2024, 9:08 p.m.)
Issued	62 years, 6 months ago (Feb. 15, 1963)
Published	62 years, 6 months ago (Feb. 15, 1963)
Published Print	62 years, 6 months ago (Feb. 15, 1963)

Funders 0

None

BibTeX

@article{Elias_1963, title={Reinvestigation of Some Absolute Rate Measurements of O-Atom Reactions with Olefins}, volume={38}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1733796}, DOI={10.1063/1.1733796}, number={4}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Elias, Lorne}, year={1963}, month=feb, pages={989–995} }

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