DOI: 10.1063/1.1733772. Transformations of Ice II, Ice III, and Ice V at Atmospheric Pressure

Transformations of Ice II, Ice III, and Ice V at Atmospheric Pressure

10.1063/1.1733772

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The transformations that occur in ices II, III, and V at atmospheric pressure when they are heated from liquid-nitrogen temperature have been examined by simple thermal analysis and by x-ray diffraction. They transform first to cubic ice I (ice Ic). The rate of transformation of ices II and III depends upon the temperature, and that of ice II probably depends upon its thermal history. The temperature dependence of the rate for ice V, and the history dependence of the rate for ices III and V were not examined. Ice Ic has previously been made only in small quantities; it can now be made in as large quantities as required by transformation of the high-pressure ices. The transformation of ice Ic to ordinary hexagonal ice (ice Ih) has also been examined. The rate depends markedly on the thermal history of the sample and this may help to explain the apparently inconsistent rates that have been reported by various workers.

Bibliography

Bertie, J. E., Calvert, L. D., & Whalley, E. (1963). Transformations of Ice II, Ice III, and Ice V at Atmospheric Pressure. The Journal of Chemical Physics, 38(4), 840â846.

Authors 3

J. E. Bertie (first)
L. D. Calvert (additional)
E. Whalley (additional)

References 20 Referenced 164

{'key': '2024020821194013900_r1', 'first-page': '1', 'volume': '2', 'year': '1900', 'journal-title': 'Ann. Phys.'} / Ann. Phys. (1900)
10.2307/20022754 / Proc. Am. Acad. Arts Sci. (1912)
10.1063/1.1749971 / J. Chem. Phys. (1937)
10.1063/1.1749561 / J. Chem. Phys. (1935)
10.1063/1.1752086 / Rev. Sci. Instr. (1936)
10.1063/1.1749748 / J. Chem. Phys. (1936)
10.1002/zaac.19090630122 / Z. Anorg. Allgem. Chem. (1909)
10.1038/187140a0 / Nature (1960)
{'key': '2024020821194013900_r5a', 'first-page': '1029', 'volume': '13', 'year': '1960', 'journal-title': 'Acta Cryst.'} / Acta Cryst. (1960)
{'key': '2024020821194013900_r6', 'first-page': '612', 'volume': '32', 'year': '1960', 'journal-title': 'J. Chem. Phys.'} / J. Chem. Phys. (1960)
10.1038/1881144a0 / Nature (1960)
10.1063/1.1731770 / J. Chem. Phys. (1961)
{'key': '2024020821194013900_r9', 'first-page': '218', 'volume': '22', 'year': '1951', 'journal-title': 'Rev. Sci. Instr.'} / Rev. Sci. Instr. (1951)
10.1107/S0365110X53000090 / Acta Cryst. (1953)
{'key': '2024020821194013900_r11'}
{'key': '2024020821194013900_r12', 'first-page': '216', 'volume': '91', 'year': '1905', 'journal-title': 'Chem. News'} / Chem. News (1905)
{'key': '2024020821194013900_r13', 'first-page': '279', 'volume': '105', 'year': '1943', 'journal-title': 'Z. Krist.'} / Z. Krist. (1943)
{'key': '2024020821194013900_r13a', 'first-page': '1', 'volume': '1', 'year': '1942', 'journal-title': 'Nachr. Akad. Wiss. Göttingen, Math.-physik. Kl.'} / Nachr. Akad. Wiss. Göttingen, Math.-physik. Kl. (1942)
{'key': '2024020821194013900_r14', 'first-page': '166', 'volume': 'A153', 'year': '1935', 'journal-title': 'Proc. Roy. Soc. (London)'} / Proc. Roy. Soc. (London) (1935)
{'key': '2024020821194013900_r15'}

Dates

Type	When
Created	20 years, 7 months ago (Jan. 9, 2005, 1:59 a.m.)
Deposited	1 year, 6 months ago (Feb. 8, 2024, 4:19 p.m.)
Indexed	2 weeks, 1 day ago (Aug. 6, 2025, 8:59 a.m.)
Issued	62 years, 6 months ago (Feb. 15, 1963)
Published	62 years, 6 months ago (Feb. 15, 1963)
Published Print	62 years, 6 months ago (Feb. 15, 1963)

Funders 0

None

BibTeX

@article{Bertie_1963, title={Transformations of Ice II, Ice III, and Ice V at Atmospheric Pressure}, volume={38}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1733772}, DOI={10.1063/1.1733772}, number={4}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Bertie, J. E. and Calvert, L. D. and Whalley, E.}, year={1963}, month=feb, pages={840–846} }

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