DOI: 10.1063/1.1733633. Gel Formation in Polymers Resulting from Simultaneous Crosslinking and Scission

Gel Formation in Polymers Resulting from Simultaneous Crosslinking and Scission

10.1063/1.1733633

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

An equation giving the gel fraction of polymers undergoing simultaneous crosslinking and scission is derived for an arbitrary initial molecular-size distribution. Application is made to the case where the initial distribution is the generalized Poisson type. For an initial distribution which is either very broad or very narrow as compared with the Poisson type and for a moderate value of the ratio of the scission rate to the crosslinking rate, considerable deviations from the Charlesby—Pinner relationship (derived for an initial random distribution) occur.

Bibliography

Inokuti, M. (1963). Gel Formation in Polymers Resulting from Simultaneous Crosslinking and Scission. The Journal of Chemical Physics, 38(12), 2999â3005.

Authors 1

Mitio Inokuti (first)

References 10 Referenced 125

{'key': '2024020821440903200_r1', 'first-page': '542', 'volume': 'A222', 'year': '1954', 'journal-title': 'Proc. Roy. Soc. (London)'} / Proc. Roy. Soc. (London) (1954)
10.1143/JPSJ.13.1451 / J. Phys. Soc. Japan (1958)
{'key': '2024020821440903200_r3', 'first-page': '120', 'volume': 'A224', 'year': '1954', 'journal-title': 'Proc. Roy. Soc. (London)'} / Proc. Roy. Soc. (London) (1954)
10.1143/JPSJ.13.198 / J. Phys. Soc. Japan (1958)
{'key': '2024020821440903200_r5', 'first-page': '367', 'volume': 'A249', 'year': '1959', 'journal-title': 'Proc. Roy. Soc. (London)'} / Proc. Roy. Soc. (London) (1959)
{'key': '2024020821440903200_r6'}
10.1063/1.1733820 / J. Chem. Phys. (1963)
10.1143/JPSJ.14.1379 / J. Phys. Soc. Japan (1959)
{'key': '2024020821440903200_r9'}
{'key': '2024020821440903200_r10'}

Dates

Type	When
Created	20 years, 7 months ago (Jan. 9, 2005, 1:59 a.m.)
Deposited	1 year, 6 months ago (Feb. 8, 2024, 4:44 p.m.)
Indexed	2 months ago (June 24, 2025, 7:43 a.m.)
Issued	62 years, 2 months ago (June 15, 1963)
Published	62 years, 2 months ago (June 15, 1963)
Published Print	62 years, 2 months ago (June 15, 1963)

Funders 0

None

BibTeX

@article{Inokuti_1963, title={Gel Formation in Polymers Resulting from Simultaneous Crosslinking and Scission}, volume={38}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1733633}, DOI={10.1063/1.1733633}, number={12}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Inokuti, Mitio}, year={1963}, month=jun, pages={2999–3005} }

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