DOI: 10.1063/1.1733498. Bonding in the Ta6Cl122+ and Mo6Cl84+ Structures

Bonding in the Ta6Cl122+ and Mo6Cl84+ Structures

10.1063/1.1733498

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

Molecular orbitals from d, s, p types of valence orbitals and parametric expressions for energy levels in octahedral Ta6Cl122+ and Mo6Cl84+ were obtained by group theoretical methods. Both cages exhibited electron delocalization and similar bonding energies, even though only the Ta6Cl122+ structure is electron deficient.

Bibliography

Crossman, L. D., Olsen, D. P., & Duffey, G. H. (1963). Bonding in the Ta6Cl122+ and Mo6Cl84+ Structures. The Journal of Chemical Physics, 38(1), 73â75.

Authors 3

Leon D. Crossman (first)
David P. Olsen (additional)
George H. Duffey (additional)

References 11 Referenced 22

10.1063/1.1740320 / J. Chem. Phys. (1954)
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10.1063/1.1732849 / J. Chem. Phys. (1962)
10.1063/1.1732850 / J. Chem. Phys. (1962)
10.1021/ja01168a028 / J. Am. Chem. Soc. (1950)
{'key': '2024020821094792300_r6'}
10.1063/1.1748417 / J. Chem. Phys. (1951)
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Dates

Type	When
Created	20 years, 7 months ago (Jan. 9, 2005, 1:59 a.m.)
Deposited	1 year, 6 months ago (Feb. 8, 2024, 4:10 p.m.)
Indexed	1 year, 6 months ago (Feb. 8, 2024, 11:03 p.m.)
Issued	62 years, 8 months ago (Jan. 1, 1963)
Published	62 years, 8 months ago (Jan. 1, 1963)
Published Print	62 years, 8 months ago (Jan. 1, 1963)

Funders 0

None

BibTeX

@article{Crossman_1963, title={Bonding in the Ta6Cl122+ and Mo6Cl84+ Structures}, volume={38}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1733498}, DOI={10.1063/1.1733498}, number={1}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Crossman, Leon D. and Olsen, David P. and Duffey, George H.}, year={1963}, month=jan, pages={73–75} }

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