Abstract
Data for the specific heat of polyethylene as a function of crystallinity are collected from 1° to 420°K. Specific heats, entropies, and enthalpies of the completely amorphous and crystalline polyethylene are extrapolated. The glass transition is located for the amorphous at 237°K with a ΔCp of 2.1 cal deg—1 (mole CH2)—1. Specific-heat values at constant volume are calculated for the crystalline polyethylene.
References
20
Referenced
131
{'key': '2024020820564208200_r1'}
10.1002/macp.1959.020340102
/ Makromol. Chem. (1959)10.1007/BFb0050500
/ Fortschr. Hochpolymer-Forsch. (1960){'key': '2024020820564208200_r3', 'first-page': '288', 'volume': '1', 'year': '1959', 'journal-title': 'Advances in Spectroscopy'}
/ Advances in Spectroscopy (1959)10.1063/1.1698724
/ J. Chem. Phys. (1953)10.1063/1.1743331
/ J. Chem. Phys. (1957){'key': '2024020820564208200_r5', 'first-page': '111', 'volume': '24', 'year': '1950', 'journal-title': 'Zhur. Fiz. Khim.'}
/ Zhur. Fiz. Khim. (1950)10.1063/1.1699152
/ J. Chem. Phys. (1953)10.1021/j100837a022
/ J. Phys. Chem. (1960)10.1063/1.1723290
/ J. Appl. Phys. (1958)10.1002/pol.1959.1203713104
/ J. Polymer Sci. (1959)10.1103/RevModPhys.32.88
/ Revs. Modern Phys. (1960)10.1021/ja01474a017
/ J. Am. Chem. Soc. (1961)10.1063/1.1743282
/ J. Chem. Phys. (1957)10.6028/jres.055.036
/ J. Research Natl. Bur. Standards (1955)10.1039/tf9494500203
/ Trans. Faraday Soc. (1949){'key': '2024020820564208200_r13', 'first-page': '55', 'volume': '76', 'year': '1948', 'journal-title': 'Proc. Am. Acad. Arts Sci.'}
/ Proc. Am. Acad. Arts Sci. (1948)10.1002/pol.1960.1204614722
/ J. Polymer Sci. (1960)10.1021/ja01546a003
/ J. Am. Chem. Soc. (1958){'key': '2024020820564208200_r16', 'first-page': '817', 'volume': '17', 'year': '1911', 'journal-title': 'Z. Elektrochem.'}
/ Z. Elektrochem. (1911)
Dates
Type | When |
---|---|
Created | 20 years, 7 months ago (Jan. 5, 2005, 10:29 p.m.) |
Deposited | 1 year, 6 months ago (Feb. 8, 2024, 3:56 p.m.) |
Indexed | 2 months ago (June 25, 2025, 6:26 p.m.) |
Issued | 62 years, 11 months ago (Sept. 15, 1962) |
Published | 62 years, 11 months ago (Sept. 15, 1962) |
Published Print | 62 years, 11 months ago (Sept. 15, 1962) |
@article{Wunderlich_1962, title={Motion in Polyethylene. I. Temperature and Crystallinity Dependence of the Specific Heat}, volume={37}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1733266}, DOI={10.1063/1.1733266}, number={6}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Wunderlich, Bernhard}, year={1962}, month=sep, pages={1203–1207} }