DOI: 10.1063/1.1733058. Reaction Kinetics of a Long Chain Molecule

Reaction Kinetics of a Long Chain Molecule

10.1063/1.1733058

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

A long chain molecule is considered, of which each segment carries a reactive group. It is assumed that the reactivity of each group depends upon whether zero, one, or two of its nearest neighbors have reacted. The average fraction of reacted groups is determined as a function of time. This is done by first deriving appropriate equations to describe the kinetics and then solving these equations. The results are illustrated by a number of graphs which show the average fraction of reacted groups as a function of time for different ratios of the reactivities.

Bibliography

Keller, J. B. (1962). Reaction Kinetics of a Long Chain Molecule. The Journal of Chemical Physics, 37(11), 2584â2586.

Authors 1

Joseph B. Keller (first)

References 9 Referenced 89

10.1021/j150519a014 / J. Phys. Chem. (1954)
10.1002/pol.1959.1204013615 / J. Polymer Sci. (1959)
{'key': '2024020821035856400_r3', 'first-page': '195', 'volume': '12', 'year': '1955', 'journal-title': 'Chem. High Polymers (Japan)'} / Chem. High Polymers (Japan) (1955)
10.1002/pol.1959.1204013616 / J. Polymer Sci. (1959)
10.1021/ja01534a060 / J. Am. Chem. Soc. (1958)
{'key': '2024020821035856400_r6'}
10.1002/pol.1958.1203212526 / J. Polymer Sci. (1958)
10.1002/pol.1960.1204514615 / J. Polymer Sci. (1960)
{'key': '2024020821035856400_r9'}

Dates

Type	When
Created	20 years, 7 months ago (Jan. 5, 2005, 10:29 p.m.)
Deposited	1 year, 6 months ago (Feb. 8, 2024, 4:04 p.m.)
Indexed	1 month, 4 weeks ago (July 4, 2025, 9:25 a.m.)
Issued	62 years, 9 months ago (Dec. 1, 1962)
Published	62 years, 9 months ago (Dec. 1, 1962)
Published Print	62 years, 9 months ago (Dec. 1, 1962)

Funders 0

None

BibTeX

@article{Keller_1962, title={Reaction Kinetics of a Long Chain Molecule}, volume={37}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1733058}, DOI={10.1063/1.1733058}, number={11}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Keller, Joseph B.}, year={1962}, month=dec, pages={2584–2586} }

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