DOI: 10.1063/1.1732982. Infrared Spectroscopic Evidence for the Rotation of the Water Molecule in Solid Argon

Infrared Spectroscopic Evidence for the Rotation of the Water Molecule in Solid Argon

10.1063/1.1732982

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

High-resolution spectra of H2O, HDO, and D2O suspended in solid Ar have been observed in the range 4°—27°K. Evidence has been obtained for the rotation of these species in Ar matrices. The majority of the observed lines are found to be in very good agreement with low-J transitions of the gas spectra, allowing for a small matrix shift. Transitions arising from both spin modifications of H2O and D2O have been observed and the observed intensities suggest that a large degree of spin equilibration has taken place. A small contamination of O2 may be responsible for this. A perturbation of one of the rotational levels of ν2—H2O is discussed.

Bibliography

Redington, R. L., & Milligan, D. E. (1962). Infrared Spectroscopic Evidence for the Rotation of the Water Molecule in Solid Argon. The Journal of Chemical Physics, 37(10), 2162â2166.

Authors 2

Richard L. Redington (first)
Dolphus E. Milligan (additional)

References 13 Referenced 147

10.1063/1.1729939 / J. Chem. Phys. (1959)
10.1063/1.1731093 / J. Chem. Phys. (1960)
10.1063/1.1732070 / J. Chem. Phys. (1961)
10.1063/1.1743753 / J. Chem. Phys. (1957)
10.1063/1.1750499 / J. Chem. Phys. (1939)
{'key': '2024020821173551700_r6'}
10.1063/1.1742731 / J. Chem. Phys. (1956)
{'key': '2024020821173551700_r8'}
{'key': '2024020821173551700_r9'}
{'key': '2024020821173551700_r10'}
10.1063/1.1730143 / J. Chem. Phys. (1959)
{'key': '2024020821173551700_r12'}
10.1143/JPSJ.11.93 / J. Phys. Soc. Japan (1956)

Dates

Type	When
Created	20 years, 7 months ago (Jan. 5, 2005, 10:29 p.m.)
Deposited	1 year, 6 months ago (Feb. 8, 2024, 4:18 p.m.)
Indexed	1 month ago (July 30, 2025, 11:27 a.m.)
Issued	62 years, 9 months ago (Nov. 15, 1962)
Published	62 years, 9 months ago (Nov. 15, 1962)
Published Print	62 years, 9 months ago (Nov. 15, 1962)

Funders 0

None

BibTeX

@article{Redington_1962, title={Infrared Spectroscopic Evidence for the Rotation of the Water Molecule in Solid Argon}, volume={37}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1732982}, DOI={10.1063/1.1732982}, number={10}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Redington, Richard L. and Milligan, Dolphus E.}, year={1962}, month=nov, pages={2162–2166} }

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