DOI: 10.1063/1.1732899. On the Self-Diffusion of Ions in a Polyelectrolyte Solution

On the Self-Diffusion of Ions in a Polyelectrolyte Solution

10.1063/1.1732899

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The self-diffusion of ions in a polyelectrolyte solution is investigated both with respect to the average time an ion is associated with a particular polyelectrolyte molecule and with respect to the effect of the electrostatic field of the macro-ions on the macroscopic self-diffusion constant. The results on the macroscopic self-diffusion constant are shown to be generally compatible with experiments on self-diffusion of counterions in polyelectrolyte solutions. On the other hand, the study of the time of association of a counterion with a particular macro-ion yields results which cannot be reconciled with the common interpretation of transference experiments on the same solutions.

Bibliography

Lifson, S., & Jackson, J. L. (1962). On the Self-Diffusion of Ions in a Polyelectrolyte Solution. The Journal of Chemical Physics, 36(9), 2410â2414.

Authors 2

Shneior Lifson (first)
Julius L. Jackson (additional)

References 11 Referenced 304

10.1021/ja01162a082 / J. Am. Chem. Soc. (1950)
10.1063/1.1700711 / J. Chem. Phys. (1952)
10.1063/1.1700712 / J. Chem. Phys. (1952)
10.1063/1.1749541 / J. Chem. Phys. (1934)
10.1021/j150519a010 / J. Phys. Chem. (1954)
10.1002/pol.1954.120136808 / J. Polymer Sci. (1954)
{'key': '2024020820382208600_r7', 'first-page': '172', 'volume': '3', 'year': '1933', 'journal-title': 'Soviet Phys.-JETP'} / Soviet Phys.-JETP (1933)
{'key': '2024020820382208600_r7a'}
{'key': '2024020820382208600_r7b', 'first-page': '431', 'volume': 'A211', 'year': '1952', 'journal-title': 'Proc. Roy. Soc. (London)'} / Proc. Roy. Soc. (London) (1952)
10.1021/ja01165a111 / J. Am. Chem. Soc. (1950)
{'key': '2024020820382208600_r9'}

Dates

Type	When
Created	20 years, 7 months ago (Jan. 5, 2005, 10:19 p.m.)
Deposited	1 year, 6 months ago (Feb. 8, 2024, 3:38 p.m.)
Indexed	3 weeks ago (Aug. 6, 2025, 9:02 a.m.)
Issued	63 years, 3 months ago (May 1, 1962)
Published	63 years, 3 months ago (May 1, 1962)
Published Print	63 years, 3 months ago (May 1, 1962)

Funders 0

None

BibTeX

@article{Lifson_1962, title={On the Self-Diffusion of Ions in a Polyelectrolyte Solution}, volume={36}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1732899}, DOI={10.1063/1.1732899}, number={9}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Lifson, Shneior and Jackson, Julius L.}, year={1962}, month=may, pages={2410–2414} }

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