DOI: 10.1063/1.1732731. Hellmann-Feynman Theorem and Correlation Energies

Hellmann-Feynman Theorem and Correlation Energies

10.1063/1.1732731

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

A proof is offered for the applicability of the Hellmann-Feynman theorem to Hartree-Fock wave functions. In conjunction with Sinanoğlu's theory of correlation energies, this leads to the idea that Hartree-Fock potential energy surfaces and exact potential energy surfaces are parallel over short distances. Finally, a new method of calculating dissociation energies is presented.

Bibliography

Stanton, R. E. (1962). Hellmann-Feynman Theorem and Correlation Energies. The Journal of Chemical Physics, 36(5), 1298â1300.

Authors 1

R. E. Stanton (first)

References 19 Referenced 106

{'key': '2024020820203298000_r1'}
10.1103/PhysRev.56.340 / Phys. Rev. (1939)
10.1063/1.1748161 / J. Chem. Phys. (1951)
{'key': '2024020820203298000_r2'}
{'key': '2024020820203298000_r3'}
10.1103/PhysRev.118.167 / Phys. Rev. (1960)
{'key': '2024020820203298000_r5', 'first-page': '379', 'volume': 'A260', 'year': '1961', 'journal-title': 'Proc. Roy. Soc. (London)'} / Proc. Roy. Soc. (London) (1961)
10.1103/PhysRev.122.491 / Phys. Rev. (1961)
10.1063/1.1731724 / J. Chem. Phys. (1961)
{'key': '2024020820203298000_r6'}
10.1103/PhysRev.112.870 / Phys. Rev. (1958)
10.1007/BF01340013 / Z. Physik (1928)
10.1007/BF01375457 / Z. Phys. (1929)
10.1007/BF01397263 / Z. Physik (1930)
10.1063/1.1730164 / J. Chem. Phys. (1959)
10.1063/1.1730166 / J. Chem. Phys. (1959)
10.1103/RevModPhys.32.219 / Revs. Modern Phys. (1960)
10.1103/RevModPhys.32.272 / Revs. Modern Phys. (1960)
10.1063/1.1731714 / J. Chem. Phys. (1961)

Dates

Type	When
Created	20 years, 7 months ago (Jan. 5, 2005, 10:19 p.m.)
Deposited	1 year, 6 months ago (Feb. 8, 2024, 3:20 p.m.)
Indexed	1 month, 2 weeks ago (July 8, 2025, 3:44 a.m.)
Issued	63 years, 5 months ago (March 1, 1962)
Published	63 years, 5 months ago (March 1, 1962)
Published Print	63 years, 5 months ago (March 1, 1962)

Funders 0

None

BibTeX

@article{Stanton_1962, title={Hellmann-Feynman Theorem and Correlation Energies}, volume={36}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1732731}, DOI={10.1063/1.1732731}, number={5}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Stanton, R. E.}, year={1962}, month=mar, pages={1298–1300} }

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