DOI: 10.1063/1.1732620. Absorption Spectra of Ferric Iron-Containing Oxides

Absorption Spectra of Ferric Iron-Containing Oxides

10.1063/1.1732620

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The interpretation of the absorption spectra of the ferric iron-containing oxides is extended and clarified. Largely on the basis of existing data it is shown that the majority of the discrete absorptions can be related to energy differences obtained from (cubic) crystal field calculations applied to Fe3+ provided a reduction of the 6S—4G separation (relative to the free ion value) is first introduced. The strong, continuous absorption which characteristically obscures the region above 20 000 cm—1 in the undiluted ferric oxides is assigned to charge transfer transitions. One low-energy absorption band (not characteristic of the iron oxides) found in the spectrum of lithium ferrite is tentatively assigned as the photoionization of a charged anion vacancy.

Bibliography

Wickersheim, K. A., & Lefever, R. A. (1962). Absorption Spectra of Ferric Iron-Containing Oxides. The Journal of Chemical Physics, 36(3), 844â850.

Authors 2

K. A. Wickersheim (first)
R. A. Lefever (additional)

References 35 Referenced 81

10.1103/PhysRev.93.1195 / Phys. Rev. (1954)
10.1063/1.1723215 / J. Appl. Phys. (1958)
10.1063/1.1723427 / J. Appl. Phys. (1958)
10.1051/jphysrad:01959002002-3037400 / J. phys. radium (1959)
10.1063/1.1984595 / J. Appl. Phys. (1960)
10.1063/1.1735136 / J. Appl. Phys. (1959)
10.1063/1.1984665 / J. Appl. Phys. (1960)
10.1051/jphysrad:01959002002-3015100 / J. Phys. Radium (1959)
{'key': '2024020820222192100_r7'}
{'key': '2024020820222192100_r8'}
{'key': '2024020820222192100_r9', 'first-page': '502', 'volume': '9', 'year': '1959', 'journal-title': 'Solid State Phys.'} / Solid State Phys. (1959)
10.1063/1.1743606 / J. Chem. Phys. (1957)
{'key': '2024020820222192100_r10'}
{'key': '2024020820222192100_r11', 'first-page': '183', 'volume': 'A227', 'year': '1955', 'journal-title': 'Proc. Roy. Soc. (London)'} / Proc. Roy. Soc. (London) (1955)
10.1063/1.1730655 / J. Chem. Phys. (1959)
{'key': '2024020820222192100_r13'}
{'key': '2024020820222192100_r14'}
10.1016/0022-3697(57)90044-6 / J. Phys. Chem. Solids (1957)
10.1103/PhysRevLett.3.207 / Phys. Rev. Letters (1959)
{'key': '2024020820222192100_r17'}
{'key': '2024020820222192100_r18'}
10.1063/1.1730968 / J. Chem. Phys. (1960)
{'key': '2024020820222192100_r20'}
10.1103/PhysRev.114.1507 / Phys. Rev. (1959)
10.1103/PhysRev.87.876 / Phys. Rev. (1952)
{'key': '2024020820222192100_r23'}
{'key': '2024020820222192100_r24', 'first-page': '217', 'volume': '8', 'year': '1959', 'journal-title': 'Solid State Phys.'} / Solid State Phys. (1959)
{'key': '2024020820222192100_r25'}
10.3891/acta.chem.scand.08-1502 / Acta Chem. Scand. (1954)
{'key': '2024020820222192100_r27'}
10.1002/recl.19360550608 / Rec. trav. chem. Pays Bas (1936)
10.1063/1.1746466 / J. Chem. Phys. (1947)
{'key': '2024020820222192100_r29'}
10.1063/1.1701242 / J. Chem. Phys. (1961)
{'key': '2024020820222192100_r30'}

Dates

Type	When
Created	20 years, 7 months ago (Jan. 5, 2005, 10:19 p.m.)
Deposited	1 year, 6 months ago (Feb. 8, 2024, 3:22 p.m.)
Indexed	9 months ago (Nov. 19, 2024, 10:52 a.m.)
Issued	63 years, 6 months ago (Feb. 1, 1962)
Published	63 years, 6 months ago (Feb. 1, 1962)
Published Print	63 years, 6 months ago (Feb. 1, 1962)

Funders 0

None

BibTeX

@article{Wickersheim_1962, title={Absorption Spectra of Ferric Iron-Containing Oxides}, volume={36}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1732620}, DOI={10.1063/1.1732620}, number={3}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Wickersheim, K. A. and Lefever, R. A.}, year={1962}, month=feb, pages={844–850} }

JSON

{
  "indexed": {
    "date-parts": [
      [
        2024,
        11,
        19
      ]
    ],
    "date-time": "2024-11-19T15:52:55Z",
    "timestamp": 1732031575847
  },
  "reference-count": 35,
  "publisher": "AIP Publishing",
  "issue": "3",
  "content-domain": {
    "domain": [
      "pubs.aip.org"
    ],
    "crossmark-restriction": true
  },
  "published-print": {
    "date-parts": [
      [
        1962,
        2,
        1
      ]
    ]
  },
  "abstract": "<jats:p>The interpretation of the absorption spectra of the ferric iron-containing oxides is extended and clarified. Largely on the basis of existing data it is shown that the majority of the discrete absorptions can be related to energy differences obtained from (cubic) crystal field calculations applied to Fe3+ provided a reduction of the 6S\u20144G separation (relative to the free ion value) is first introduced. The strong, continuous absorption which characteristically obscures the region above 20 000 cm\u20141 in the undiluted ferric oxides is assigned to charge transfer transitions. One low-energy absorption band (not characteristic of the iron oxides) found in the spectrum of lithium ferrite is tentatively assigned as the photoionization of a charged anion vacancy.</jats:p>",
  "DOI": "10.1063/1.1732620",
  "type": "journal-article",
  "created": {
    "date-parts": [
      [
        2005,
        1,
        6
      ]
    ],
    "date-time": "2005-01-06T03:19:39Z",
    "timestamp": 1104981579000
  },
  "page": "844-850",
  "update-policy": "http://dx.doi.org/10.1063/aip-crossmark-policy-page",
  "source": "Crossref",
  "is-referenced-by-count": 81,
  "title": "Absorption Spectra of Ferric Iron-Containing Oxides",
  "prefix": "10.1063",
  "volume": "36",
  "author": [
    {
      "given": "K. A.",
      "family": "Wickersheim",
      "sequence": "first",
      "affiliation": [
        {
          "name": "General Telephone and Electronics Laboratories, Inc., Palo Alto, California"
        }
      ]
    },
    {
      "given": "R. A.",
      "family": "Lefever",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "General Telephone and Electronics Laboratories, Inc., Palo Alto, California"
        }
      ]
    }
  ],
  "member": "317",
  "reference": [
    {
      "key": "2024020820222192100_r1",
      "doi-asserted-by": "crossref",
      "first-page": "1195",
      "DOI": "10.1103/PhysRev.93.1195",
      "volume": "93",
      "year": "1954",
      "journal-title": "Phys. Rev."
    },
    {
      "key": "2024020820222192100_r2",
      "doi-asserted-by": "crossref",
      "first-page": "539",
      "DOI": "10.1063/1.1723215",
      "volume": "29",
      "year": "1958",
      "journal-title": "J. Appl. Phys."
    },
    {
      "key": "2024020820222192100_r2a",
      "doi-asserted-by": "crossref",
      "first-page": "1286",
      "DOI": "10.1063/1.1723427",
      "volume": "29",
      "year": "1958",
      "journal-title": "J. Appl. Phys."
    },
    {
      "key": "2024020820222192100_r2b",
      "doi-asserted-by": "crossref",
      "first-page": "374",
      "DOI": "10.1051/jphysrad:01959002002-3037400",
      "volume": "20",
      "year": "1959",
      "journal-title": "J. phys. radium"
    },
    {
      "key": "2024020820222192100_r3",
      "doi-asserted-by": "crossref",
      "first-page": "39S",
      "DOI": "10.1063/1.1984595",
      "volume": "31",
      "year": "1960",
      "journal-title": "J. Appl. Phys."
    },
    {
      "key": "2024020820222192100_r4",
      "doi-asserted-by": "crossref",
      "first-page": "217",
      "DOI": "10.1063/1.1735136",
      "volume": "30",
      "year": "1959",
      "journal-title": "J. Appl. Phys."
    },
    {
      "key": "2024020820222192100_r5",
      "doi-asserted-by": "crossref",
      "first-page": "198S",
      "DOI": "10.1063/1.1984665",
      "volume": "31",
      "year": "1960",
      "journal-title": "J. Appl. Phys."
    },
    {
      "key": "2024020820222192100_r6",
      "doi-asserted-by": "crossref",
      "first-page": "151",
      "DOI": "10.1051/jphysrad:01959002002-3015100",
      "volume": "20",
      "year": "1959",
      "journal-title": "J. Phys. Radium"
    },
    {
      "key": "2024020820222192100_r7"
    },
    {
      "key": "2024020820222192100_r8"
    },
    {
      "key": "2024020820222192100_r9",
      "first-page": "502",
      "volume": "9",
      "year": "1959",
      "journal-title": "Solid State Phys."
    },
    {
      "key": "2024020820222192100_r9a",
      "doi-asserted-by": "crossref",
      "first-page": "1686",
      "DOI": "10.1063/1.1743606",
      "volume": "26",
      "year": "1957",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020820222192100_r10"
    },
    {
      "key": "2024020820222192100_r11",
      "first-page": "183",
      "volume": "A227",
      "year": "1955",
      "journal-title": "Proc. Roy. Soc. (London)"
    },
    {
      "key": "2024020820222192100_r12",
      "doi-asserted-by": "crossref",
      "first-page": "1579",
      "DOI": "10.1063/1.1730655",
      "volume": "31",
      "year": "1959",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020820222192100_r13"
    },
    {
      "key": "2024020820222192100_r14"
    },
    {
      "key": "2024020820222192100_r15",
      "doi-asserted-by": "crossref",
      "first-page": "30",
      "DOI": "10.1016/0022-3697(57)90044-6",
      "volume": "3",
      "year": "1957",
      "journal-title": "J. Phys. Chem. Solids"
    },
    {
      "key": "2024020820222192100_r16",
      "doi-asserted-by": "crossref",
      "first-page": "207",
      "DOI": "10.1103/PhysRevLett.3.207",
      "volume": "3",
      "year": "1959",
      "journal-title": "Phys. Rev. Letters"
    },
    {
      "key": "2024020820222192100_r17"
    },
    {
      "key": "2024020820222192100_r18"
    },
    {
      "key": "2024020820222192100_r19",
      "doi-asserted-by": "crossref",
      "first-page": "1575",
      "DOI": "10.1063/1.1730968",
      "volume": "32",
      "year": "1960",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020820222192100_r20"
    },
    {
      "key": "2024020820222192100_r21",
      "doi-asserted-by": "crossref",
      "first-page": "1507",
      "DOI": "10.1103/PhysRev.114.1507",
      "volume": "114",
      "year": "1959",
      "journal-title": "Phys. Rev."
    },
    {
      "key": "2024020820222192100_r22",
      "doi-asserted-by": "crossref",
      "first-page": "876",
      "DOI": "10.1103/PhysRev.87.876",
      "volume": "87",
      "year": "1952",
      "journal-title": "Phys. Rev."
    },
    {
      "key": "2024020820222192100_r23"
    },
    {
      "key": "2024020820222192100_r24",
      "first-page": "217",
      "volume": "8",
      "year": "1959",
      "journal-title": "Solid State Phys."
    },
    {
      "key": "2024020820222192100_r25"
    },
    {
      "key": "2024020820222192100_r26",
      "doi-asserted-by": "crossref",
      "first-page": "1502",
      "DOI": "10.3891/acta.chem.scand.08-1502",
      "volume": "8",
      "year": "1954",
      "journal-title": "Acta Chem. Scand."
    },
    {
      "key": "2024020820222192100_r27"
    },
    {
      "key": "2024020820222192100_r28",
      "doi-asserted-by": "crossref",
      "first-page": "531",
      "DOI": "10.1002/recl.19360550608",
      "volume": "55",
      "year": "1936",
      "journal-title": "Rec. trav. chem. Pays Bas"
    },
    {
      "key": "2024020820222192100_r28a",
      "doi-asserted-by": "crossref",
      "first-page": "181",
      "DOI": "10.1063/1.1746466",
      "volume": "15",
      "year": "1947",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020820222192100_r29"
    },
    {
      "key": "2024020820222192100_r29a",
      "doi-asserted-by": "crossref",
      "first-page": "940",
      "DOI": "10.1063/1.1701242",
      "volume": "35",
      "year": "1961",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020820222192100_r30"
    }
  ],
  "container-title": "The Journal of Chemical Physics",
  "original-title": [],
  "language": "en",
  "link": [
    {
      "URL": "https://pubs.aip.org/aip/jcp/article-pdf/36/3/844/18823995/844_1_online.pdf",
      "content-type": "application/pdf",
      "content-version": "vor",
      "intended-application": "syndication"
    },
    {
      "URL": "https://pubs.aip.org/aip/jcp/article-pdf/36/3/844/18823995/844_1_online.pdf",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "similarity-checking"
    }
  ],
  "deposited": {
    "date-parts": [
      [
        2024,
        2,
        8
      ]
    ],
    "date-time": "2024-02-08T20:22:43Z",
    "timestamp": 1707423763000
  },
  "score": 1,
  "resource": {
    "primary": {
      "URL": "https://pubs.aip.org/jcp/article/36/3/844/205941/Absorption-Spectra-of-Ferric-Iron-Containing"
    }
  },
  "subtitle": [],
  "short-title": [],
  "issued": {
    "date-parts": [
      [
        1962,
        2,
        1
      ]
    ]
  },
  "references-count": 35,
  "journal-issue": {
    "issue": "3",
    "published-print": {
      "date-parts": [
        [
          1962,
          2,
          1
        ]
      ]
    }
  },
  "URL": "http://dx.doi.org/10.1063/1.1732620",
  "relation": {},
  "ISSN": [
    "0021-9606",
    "1089-7690"
  ],
  "subject": [],
  "published-other": {
    "date-parts": [
      [
        1962,
        2,
        1
      ]
    ]
  },
  "published": {
    "date-parts": [
      [
        1962,
        2,
        1
      ]
    ]
  }
}