DOI: 10.1063/1.1732506. Infrared Spectra of Metal Chelate Compounds. VIII. Infrared Spectra of Co(III) Carbonato Complexes

Infrared Spectra of Metal Chelate Compounds. VIII. Infrared Spectra of Co(III) Carbonato Complexes

10.1063/1.1732506

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The infrared spectra of twenty Co(III) carbonato complexes have been measured in a range between 4000 and 300 cm—1. Normal coordinate treatments were made with a model based on the unidentate and bidentate forms of the 1:1 (metal/ligand) complex. The theoretical band assignments and force constants obtained by these calculations confirm the validity of the previous qualitative conclusions based on the differences of symmetry and the frequency shifts of the unidentate and bidentate complexes. The Co(III)-O stretching bands were located at 440∼380 (antisymmetric) and at 400∼350 (symmetric) for the bidentate complexes, and at 360∼340 cm—1 for the unidentate complexes.

Bibliography

Fujita, J., Martell, A. E., & Nakamoto, K. (1962). Infrared Spectra of Metal Chelate Compounds. VIII. Infrared Spectra of Co(III) Carbonato Complexes. The Journal of Chemical Physics, 36(2), 339â345.

Authors 3

Junnosuke Fujita (first)
Arthur E. Martell (additional)
Kazuo Nakamoto (additional)

References 16 Referenced 154

10.1021/ja01575a020 / J. Am. Chem. Soc. (1957)
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10.1063/1.1730741 / J. Chem. Phys. (1960)
10.1021/ja01466a014 / J. Am. Chem. Soc. (1961)
10.1021/ja01524a003 / J. Am. Chem. Soc. (1959)
{'key': '2024020820261377100_r5'}
10.1246/bcsj.29.904 / Bull. Chem. Soc. Japan (1956)
{'key': '2024020820261377100_r5b', 'first-page': '72', 'volume': '386', 'year': '1912', 'journal-title': 'Ann.'} / Ann. (1912)
10.1021/ja01104a019 / J. Am. Chem. Soc. (1953)
10.1002/zaac.19492600106 / Z. anorg. u. allgem. Chem. (1949)
10.1246/bcsj.29.311 / Bull. Chem. Soc. Japan (1956)
10.1063/1.1747232 / J. Chem. Phys. (1949)
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Dates

Type	When
Created	20 years, 7 months ago (Jan. 5, 2005, 10:19 p.m.)
Deposited	1 year, 6 months ago (Feb. 8, 2024, 3:26 p.m.)
Indexed	1 week, 2 days ago (Aug. 19, 2025, 6:35 a.m.)
Issued	63 years, 7 months ago (Jan. 15, 1962)
Published	63 years, 7 months ago (Jan. 15, 1962)
Published Print	63 years, 7 months ago (Jan. 15, 1962)

Funders 0

None

BibTeX

@article{Fujita_1962, title={Infrared Spectra of Metal Chelate Compounds. VIII. Infrared Spectra of Co(III) Carbonato Complexes}, volume={36}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1732506}, DOI={10.1063/1.1732506}, number={2}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Fujita, Junnosuke and Martell, Arthur E. and Nakamoto, Kazuo}, year={1962}, month=jan, pages={339–345} }

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