DOI: 10.1063/1.1732408. Centrifugal Distortion of Bond Distances and Bond Angles

Centrifugal Distortion of Bond Distances and Bond Angles

10.1063/1.1732408

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

A simple method has been developed to estimate the changes of bond distances and bond angles produced by the centrifugal force arising from rotational motions of molecules. The method has been applied to the PCl3 molecule and the predicted effect found to be small but significant in comparison to the effect of vibrational motion. The theoretical results for PCl3 at 300° and 505°K are in good agreement with experimental results from gaseous electron diffraction.

Authors 2

Machio Iwasaki (first)
Kenneth Hedberg (additional)

References 6 Referenced 65

10.1063/1.1732575 / J. Chem. Phys. (1962)
10.1063/1.1730774 / J. Chem. Phys. (1960)
10.1063/1.1750363 / J. Chem. Phys.
10.1063/1.1750829 / J. Chem. Phys. (1941)
{'key': '2024020820452694900_r4'}
10.1063/1.1732576 / J. Chem. Phys. (1962)

Dates

Type	When
Created	20 years, 7 months ago (Jan. 5, 2005, 10:19 p.m.)
Deposited	1 year, 6 months ago (Feb. 8, 2024, 3:45 p.m.)
Indexed	2 months ago (June 24, 2025, 12:29 p.m.)
Issued	63 years, 2 months ago (June 1, 1962)
Published	63 years, 2 months ago (June 1, 1962)
Published Print	63 years, 2 months ago (June 1, 1962)

Funders 0

None

BibTeX

@article{Iwasaki_1962, title={Centrifugal Distortion of Bond Distances and Bond Angles}, volume={36}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1732408}, DOI={10.1063/1.1732408}, number={11}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Iwasaki, Machio and Hedberg, Kenneth}, year={1962}, month=jun, pages={2961–2963} }

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