DOI: 10.1063/1.1732284. Solid-State Vibrational Spectra of Ethylene and Ethylene-<i>d</i>4

Solid-State Vibrational Spectra of Ethylene and Ethylene-d4

10.1063/1.1732284

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

High-resolution infrared spectra have been obtained for polycrystalline C2H4 at 4° and 53°K and for C2D4 at 53°K. The observed multiplet structure of the fundamental vibrations is in good agreement with the group theoretical predictions. In C2H4 there is evidence for a gradual phase transition between 4° and 53°K, involving reorientation of the planes of the H atoms of C2H4 molecules in the crystal. The Raman-active fundamentals have been observed, weakly, in thick deposits of C2H4 at 4°K.

Bibliography

Jacox, M. E. (1962). Solid-State Vibrational Spectra of Ethylene and Ethylene-d4. The Journal of Chemical Physics, 36(1), 140â143.

Authors 1

Marilyn E. Jacox (first)

References 7 Referenced 44

10.1039/tf9444000023 / Trans. Faraday Soc. (1944)
{'key': '2024020820134873900_r2'}
10.1063/1.1701188 / J. Chem. Phys. (1961)
10.1063/1.1731887 / J. Chem. Phys. (1961)
10.1063/1.1747428 / J. Chem. Phys. (1950)
10.1021/ja01286a031 / J. Am. Chem. Soc. (1937)
10.1016/0371-1951(61)80167-7 / Spectrochim. Acta (1961)

Dates

Type	When
Created	20 years, 7 months ago (Jan. 5, 2005, 10:19 p.m.)
Deposited	1 year, 6 months ago (Feb. 8, 2024, 3:13 p.m.)
Indexed	1 week, 1 day ago (Aug. 22, 2025, 12:46 a.m.)
Issued	63 years, 7 months ago (Jan. 1, 1962)
Published	63 years, 7 months ago (Jan. 1, 1962)
Published Print	63 years, 7 months ago (Jan. 1, 1962)

Funders 0

None

BibTeX

@article{Jacox_1962, title={Solid-State Vibrational Spectra of Ethylene and Ethylene-d4}, volume={36}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1732284}, DOI={10.1063/1.1732284}, number={1}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Jacox, Marilyn E.}, year={1962}, month=jan, pages={140–143} }

JSON

{
  "indexed": {
    "date-parts": [
      [
        2025,
        8,
        22
      ]
    ],
    "date-time": "2025-08-22T04:46:31Z",
    "timestamp": 1755837991317
  },
  "reference-count": 7,
  "publisher": "AIP Publishing",
  "issue": "1",
  "content-domain": {
    "domain": [
      "pubs.aip.org"
    ],
    "crossmark-restriction": true
  },
  "published-print": {
    "date-parts": [
      [
        1962,
        1,
        1
      ]
    ]
  },
  "abstract": "<jats:p>High-resolution infrared spectra have been obtained for polycrystalline C2H4 at 4\u00b0 and 53\u00b0K and for C2D4 at 53\u00b0K. The observed multiplet structure of the fundamental vibrations is in good agreement with the group theoretical predictions. In C2H4 there is evidence for a gradual phase transition between 4\u00b0 and 53\u00b0K, involving reorientation of the planes of the H atoms of C2H4 molecules in the crystal. The Raman-active fundamentals have been observed, weakly, in thick deposits of C2H4 at 4\u00b0K.</jats:p>",
  "DOI": "10.1063/1.1732284",
  "type": "journal-article",
  "created": {
    "date-parts": [
      [
        2005,
        1,
        6
      ]
    ],
    "date-time": "2005-01-06T03:19:39Z",
    "timestamp": 1104981579000
  },
  "page": "140-143",
  "update-policy": "http://dx.doi.org/10.1063/aip-crossmark-policy-page",
  "source": "Crossref",
  "is-referenced-by-count": 44,
  "title": "Solid-State Vibrational Spectra of Ethylene and Ethylene-<i>d</i>4",
  "prefix": "10.1063",
  "volume": "36",
  "author": [
    {
      "given": "Marilyn E.",
      "family": "Jacox",
      "sequence": "first",
      "affiliation": [
        {
          "name": "Mellon Institute, Pittsburgh, Pennsylvania"
        }
      ]
    }
  ],
  "member": "317",
  "reference": [
    {
      "key": "2024020820134873900_r1",
      "doi-asserted-by": "crossref",
      "first-page": "23",
      "DOI": "10.1039/tf9444000023",
      "volume": "40",
      "year": "1944",
      "journal-title": "Trans. Faraday Soc."
    },
    {
      "key": "2024020820134873900_r2"
    },
    {
      "key": "2024020820134873900_r2a",
      "doi-asserted-by": "crossref",
      "first-page": "1109",
      "DOI": "10.1063/1.1701188",
      "volume": "35",
      "year": "1961",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020820134873900_r3",
      "doi-asserted-by": "crossref",
      "first-page": "183",
      "DOI": "10.1063/1.1731887",
      "volume": "35",
      "year": "1961",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020820134873900_r4",
      "doi-asserted-by": "crossref",
      "first-page": "118",
      "DOI": "10.1063/1.1747428",
      "volume": "18",
      "year": "1950",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020820134873900_r5",
      "doi-asserted-by": "crossref",
      "first-page": "1264",
      "DOI": "10.1021/ja01286a031",
      "volume": "59",
      "year": "1937",
      "journal-title": "J. Am. Chem. Soc."
    },
    {
      "key": "2024020820134873900_r6",
      "doi-asserted-by": "crossref",
      "first-page": "1196",
      "DOI": "10.1016/0371-1951(61)80167-7",
      "volume": "17",
      "year": "1961",
      "journal-title": "Spectrochim. Acta"
    }
  ],
  "container-title": "The Journal of Chemical Physics",
  "original-title": [],
  "language": "en",
  "link": [
    {
      "URL": "https://pubs.aip.org/aip/jcp/article-pdf/36/1/140/18823598/140_1_online.pdf",
      "content-type": "application/pdf",
      "content-version": "vor",
      "intended-application": "syndication"
    },
    {
      "URL": "https://pubs.aip.org/aip/jcp/article-pdf/36/1/140/18823598/140_1_online.pdf",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "similarity-checking"
    }
  ],
  "deposited": {
    "date-parts": [
      [
        2024,
        2,
        8
      ]
    ],
    "date-time": "2024-02-08T20:13:55Z",
    "timestamp": 1707423235000
  },
  "score": 1,
  "resource": {
    "primary": {
      "URL": "https://pubs.aip.org/jcp/article/36/1/140/205591/Solid-State-Vibrational-Spectra-of-Ethylene-and"
    }
  },
  "subtitle": [],
  "short-title": [],
  "issued": {
    "date-parts": [
      [
        1962,
        1,
        1
      ]
    ]
  },
  "references-count": 7,
  "journal-issue": {
    "issue": "1",
    "published-print": {
      "date-parts": [
        [
          1962,
          1,
          1
        ]
      ]
    }
  },
  "URL": "http://dx.doi.org/10.1063/1.1732284",
  "relation": {},
  "ISSN": [
    "0021-9606",
    "1089-7690"
  ],
  "subject": [],
  "published-other": {
    "date-parts": [
      [
        1962,
        1,
        1
      ]
    ]
  },
  "published": {
    "date-parts": [
      [
        1962,
        1,
        1
      ]
    ]
  }
}