DOI: 10.1063/1.1732227. Raman Spectra of Metal Carbonyl Compounds. IV. Raman Spectra and Structure of Cadmium and Mercury Cobalt Carbonyl

Raman Spectra of Metal Carbonyl Compounds. IV. Raman Spectra and Structure of Cadmium and Mercury Cobalt Carbonyl

10.1063/1.1732227

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The complete Raman spectrum of Cd[Co(CO)4]2 and a partial one of Hg[Co(CO)4]2, excited by helium radiation in the red and near infrared spectral range, are reported. A salient feature of the observed spectra is the appearance of an intense, strongly polarized shift at 152 (161) cm—1, not found in the spectra of mononuclear metal carbonyls, that must be assigned to the symmetric Cd(Hg)–Co stretching mode. The results exclude the presence of one or more bridging CO groups in the compounds referred to and point strongly to both the existence of a three-fold principal molecular axis containing the atoms O–C–Co–Cd(Hg)–Co–C–O, and to the staggered D3d configuration of the entire molecule.

Bibliography

Stammreich, H., Kawai, K., Sala, Osw., & Krumholz, P. (1961). Raman Spectra of Metal Carbonyl Compounds. IV. Raman Spectra and Structure of Cadmium and Mercury Cobalt Carbonyl. The Journal of Chemical Physics, 35(6), 2175â2179.

Authors 4

H. Stammreich (first)
K. Kawai (additional)
Osw. Sala (additional)
P. Krumholz (additional)

References 11 Referenced 38

10.1021/cr50007a001 / Chem. Revs. (1956)
10.1002/zaac.19422490104 / Z. anorg. u. allgem. Chem. (1942)
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10.1039/qr9470100331 / Quart Revs. (London) (1947)
10.1016/0371-1951(60)80152-X / Spectrochim. Acta (1960)
10.1063/1.1730068 / J. Chem. Phys. (1959)
10.1063/1.1730945 / J. Chem. Phys. (1960)
10.1063/1.1732226 / J. Chem. Phys. (1961)
10.1002/zaac.19522690418 / Z. anorg. u. allgem. Chem. (1952)
10.1021/ja01598a001 / J. Am. Chem. Soc. (1956)
10.1021/ja01598a002 / J. Am. Chem. Soc. (1956)

Dates

Type	When
Created	20 years, 7 months ago (Jan. 5, 2005, 10:07 p.m.)
Deposited	1 year, 6 months ago (Feb. 8, 2024, 3:17 p.m.)
Indexed	1 year, 6 months ago (Feb. 8, 2024, 3:40 p.m.)
Issued	63 years, 9 months ago (Dec. 1, 1961)
Published	63 years, 9 months ago (Dec. 1, 1961)
Published Print	63 years, 9 months ago (Dec. 1, 1961)

Funders 0

None

BibTeX

@article{Stammreich_1961, title={Raman Spectra of Metal Carbonyl Compounds. IV. Raman Spectra and Structure of Cadmium and Mercury Cobalt Carbonyl}, volume={35}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1732227}, DOI={10.1063/1.1732227}, number={6}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Stammreich, H. and Kawai, K. and Sala, Osw. and Krumholz, P.}, year={1961}, month=dec, pages={2175–2179} }

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