DOI: 10.1063/1.1732112. Compressibility of Simple Fused Salts

10.1063/1.1732112

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

It is pointed out that the isothermal compressibility of monatomic molten salts should nearly equal that for a hypothetical fluid of uncharged ion cores at the same over-all particle density as the salt. The validity of this relation is equivalent to verification of conjectures concerning the number-average correlation function for ion pairs in the melt. When the ion core forces are treated as those acting between rigid spheres, it is readily possible to predict the distance of closest approach for an anion-cation pair from experimentally determined compressibilities. The corresponding distances obtained in this manner for a series of molten halides are consistent with known ion sizes, and furthermore exhibit the proper homologous series trends.

Bibliography

Stillinger, F. H. (1961). Compressibility of Simple Fused Salts. The Journal of Chemical Physics, 35(5), 1581â1583.

Authors 1

Frank H. Stillinger (first)

References 13 Referenced 36

10.1063/1.1731031 / J. Chem. Phys. (1960)
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10.1063/1.1747854 / J. Chem. Phys. (1950)
10.1063/1.1730361 / J. Chem. Phys. (1959)
10.1063/1.1743956 / J. Chem. Phys. (1957)
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10.1021/j150542a023 / J. Phys. Chem. (1956)
10.1021/j150468a006 / J. Phys. Chem. (1949)
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Dates

Type	When
Created	20 years, 7 months ago (Jan. 5, 2005, 10:07 p.m.)
Deposited	1 year, 6 months ago (Feb. 8, 2024, 3:13 p.m.)
Indexed	3 months, 3 weeks ago (May 8, 2025, 5:04 p.m.)
Issued	63 years, 10 months ago (Nov. 1, 1961)
Published	63 years, 10 months ago (Nov. 1, 1961)
Published Print	63 years, 10 months ago (Nov. 1, 1961)

Funders 0

None

BibTeX

@article{Stillinger_1961, title={Compressibility of Simple Fused Salts}, volume={35}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1732112}, DOI={10.1063/1.1732112}, number={5}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Stillinger, Frank H.}, year={1961}, month=nov, pages={1581–1583} }

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