DOI: 10.1063/1.1732070. Infrared Spectroscopic Study of the Photolysis of Methyl Azide and Methyl-<i>d</i>3 Azide in Solid Argon and Carbon Dioxide

Infrared Spectroscopic Study of the Photolysis of Methyl Azide and Methyl-d3 Azide in Solid Argon and Carbon Dioxide

10.1063/1.1732070

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

Experiments have been carried out on the photolysis of methyl azide and methyl-d3 azide at high dilution in solid argon (4.2°K) and carbon dioxide (∼50°K). Photolysis of these species in argon and carbon dioxide matrices results in the appearance of a number of new spectral features in the 3300–600 cm—1 region. The spectroscopic data for the photolysis products appear to be consistent with the identification of these species as methyleneimine (CH2=NH) and methyleneimine-d3 (CD2=ND).

Bibliography

Milligan, D. E. (1961). Infrared Spectroscopic Study of the Photolysis of Methyl Azide and Methyl-d3 Azide in Solid Argon and Carbon Dioxide. The Journal of Chemical Physics, 35(4), 1491â1497.

Authors 1

Dolphus E. Milligan (first)

References 13 Referenced 145

10.1021/ja01394a006 / J. Am. Chem. Soc. (1928)
10.1021/ja01364a020 / J. Am. Chem. Soc. (1930)
10.1021/ja01335a007 / J. Am. Chem. Soc. (1933)
10.1021/j150552a044 / J. Phys. Chem. (1957)
10.1063/1.1742860 / J. Chem. Phys. (1956)
{'key': '2024020820184711200_r5', 'first-page': '53', 'volume': '90', 'year': '1960', 'journal-title': 'Gazz. Chim. Ital.'} / Gazz. Chim. Ital. (1960)
10.1021/j150550a016 / J. Phys. Chem. (1957)
{'key': '2024020820184711200_r7'}
{'key': '2024020820184711200_r8', 'first-page': '5169', 'volume': '76', 'year': '1954', 'journal-title': 'J. Am. Chem. Soc.'} / J. Am. Chem. Soc. (1954)
10.1524/zpch.1956.6.1_2.083 / Z. Physik. Chem. (1956)
{'key': '2024020820184711200_r10'}
10.1063/1.1747428 / J. Chem. Phys. (1950)
{'key': '2024020820184711200_r12'}

Dates

Type	When
Created	20 years, 8 months ago (Jan. 5, 2005, 10:07 p.m.)
Deposited	1 year, 6 months ago (Feb. 8, 2024, 3:19 p.m.)
Indexed	1 month, 1 week ago (July 27, 2025, 3:41 a.m.)
Issued	63 years, 11 months ago (Oct. 1, 1961)
Published	63 years, 11 months ago (Oct. 1, 1961)
Published Print	63 years, 11 months ago (Oct. 1, 1961)

Funders 0

None

BibTeX

@article{Milligan_1961, title={Infrared Spectroscopic Study of the Photolysis of Methyl Azide and Methyl-d3 Azide in Solid Argon and Carbon Dioxide}, volume={35}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1732070}, DOI={10.1063/1.1732070}, number={4}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Milligan, Dolphus E.}, year={1961}, month=oct, pages={1491–1497} }

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