DOI: 10.1063/1.1732065. Diffusion of Neon Isotopes in Fused Quartz

Diffusion of Neon Isotopes in Fused Quartz

10.1063/1.1732065

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The diffusion of Ne20 and Ne22 through the walls of high-purity fused quartz hollow cylinders was studied using a mass spectrometer as a detecting device. The diffusion process was found to be relatively simple and fairly well described by Fick's laws. Diffusion coefficients and permeabilities were measured for both isotopes in the temperature range of 440° to 985°C. The D0's for Ne20 and Ne22 were (2.21±0.12) × 10—4 cm2/sec and (2.08±0.17) × 10—4 cm2/sec respectively. The activation energy for diffusion for Ne20 was 11 370±80 cal/g atom and the value for Ne22 was found to be statistically equivalent to this. The best estimate of the ratio of the D0's was 1.05±0.01. Solubilities were calculated by dividing the permeabilities by the diffusion coefficients. The heats of solution for the two isotopes were the same and equal to — 1950±150 cal/g atom. The significance of the isotope effect in diffusion is discussed.

Bibliography

Frank, R. C., Swets, D. E., & Lee, R. W. (1961). Diffusion of Neon Isotopes in Fused Quartz. The Journal of Chemical Physics, 35(4), 1451â1459.

Authors 3

R. C. Frank (first)
D. E. Swets (additional)
R. W. Lee (additional)

References 27 Referenced 59

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Dates

Type	When
Created	20 years, 7 months ago (Jan. 5, 2005, 10:07 p.m.)
Deposited	1 year, 6 months ago (Feb. 8, 2024, 3:13 p.m.)
Indexed	4 months ago (May 2, 2025, 12:07 a.m.)
Issued	63 years, 11 months ago (Oct. 1, 1961)
Published	63 years, 11 months ago (Oct. 1, 1961)
Published Print	63 years, 11 months ago (Oct. 1, 1961)

Funders 0

None

BibTeX

@article{Frank_1961, title={Diffusion of Neon Isotopes in Fused Quartz}, volume={35}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1732065}, DOI={10.1063/1.1732065}, number={4}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Frank, R. C. and Swets, D. E. and Lee, R. W.}, year={1961}, month=oct, pages={1451–1459} }

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