DOI: 10.1063/1.1732026. Low-Resolution Analysis of the <i>n</i>→π* (3000 A) Absorption Spectrum of <i>s</i>-Triazine

Low-Resolution Analysis of the n→π* (3000 A) Absorption Spectrum of s-Triazine

10.1063/1.1732026

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The 3000-A absorption band of s-triazine has been examined under low resolution. The long wavelength portion of this band is assigned to the allowed n→π* promotion A2′′1← A1′1 with 0–0 band at 31 574±15 cm—1. Evidence is presented for the onset of a second n→π* transition at ∼32 500 cm—1. The observed sequence of states contradicts previous predictions based on approximate sp2 hybridization, and indicates that in the excited states the n orbital has very little s character (∼0.1).

Bibliography

Brinen, J. S., & Goodman, L. (1961). Low-Resolution Analysis of the nâÏ* (3000 A) Absorption Spectrum of s-Triazine. The Journal of Chemical Physics, 35(4), 1219â1225.

Authors 2

J. S. Brinen (first)
Lionel Goodman (additional)

References 18 Referenced 21

10.1063/1.1740306 / J. Chem. Phys. (1954)
10.1016/0022-2852(61)90235-1 / J. Mol. Spectroscopy (1961)
10.1063/1.1730380 / J. Chem. Phys. (1959)
10.1063/1.1700572 / J. Chem. Phys. (1952)
{'key': '2024020820020396800_r5', 'first-page': '1149', 'volume': '22', 'year': '1954', 'journal-title': 'J. Chem. Phys.'} / J. Chem. Phys. (1954)
10.1063/1.1740381 / J. Chem. Phys. (1954)
10.1021/j150522a008 / J. Phys. Chem. (1954)
10.1016/0371-1951(60)80054-9 / Spectrochim. Acta (1960)
10.1038/187500a0 / Nature (1960)
{'key': '2024020820020396800_r10'}
10.1103/RevModPhys.13.75 / Revs. Modern Phys. (1941)
{'key': '2024020820020396800_r12'}
10.1063/1.1743989 / J. Chem. Phys. (1957)
10.1063/1.1731071 / J. Chem. Phys. (1960)
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{'key': '2024020820020396800_r18', 'first-page': '220', 'volume': 'A161', 'year': '1937', 'journal-title': 'Proc. Roy. Soc. (London)'} / Proc. Roy. Soc. (London) (1937)

Dates

Type	When
Created	20 years, 7 months ago (Jan. 5, 2005, 10:07 p.m.)
Deposited	1 year, 6 months ago (Feb. 8, 2024, 3:02 p.m.)
Indexed	1 year, 6 months ago (Feb. 9, 2024, 5:57 p.m.)
Issued	63 years, 11 months ago (Oct. 1, 1961)
Published	63 years, 11 months ago (Oct. 1, 1961)
Published Print	63 years, 11 months ago (Oct. 1, 1961)

Funders 0

None

BibTeX

@article{Brinen_1961, title={Low-Resolution Analysis of the n→π* (3000 A) Absorption Spectrum of s-Triazine}, volume={35}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1732026}, DOI={10.1063/1.1732026}, number={4}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Brinen, J. S. and Goodman, Lionel}, year={1961}, month=oct, pages={1219–1225} }

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