DOI: 10.1063/1.1730904. Nuclear Magnetic Resonance in B2O3

Nuclear Magnetic Resonance in B2O3–H2O Glasses and Boric Acids

10.1063/1.1730904

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The class of materials B2O3–H2O has been investigated over the range B2O3 to B2O3·3H2O. This includes ``dry'' glassy B2O3, ``wet'' glassy boron oxide of approximate composition B2O3·½H2O, monoclinic and orthorhombic forms of metaboric acid, B2O3·H2O, and triclinic orthoboric acid, B2O3·3H2O. The nuclear quadrupole interaction of the B11 isotope was measured and comparisons of the structures are made on the basis of this interaction. It is shown that all substances contain similar planar BO3 triangular units. The presence of O–H–O hydrogen bonds, as in B2O3·3H2O, has a minor effect on the boron nuclear quadrupole interaction. It is concluded that BO4 tetrahedral units exist in several of the wet glass samples as well as in monoclinic metaboric acid.

Bibliography

Silver, A. H. (1960). Nuclear Magnetic Resonance in B2O3âH2O Glasses and Boric Acids. The Journal of Chemical Physics, 32(4), 959â962.

Authors 1

A. H. Silver (first)

References 10 Referenced 47

10.1063/1.1744697 / J. Chem. Phys. (1958)
10.1063/1.1730278 / J. Chem. Phys. (1959)
{'key': '2024020819084880400_r3', 'first-page': '55', 'volume': 'A10', 'year': '1940', 'journal-title': 'J. Sci. Hiroshima Univ.'} / J. Sci. Hiroshima Univ. (1940)
10.1107/S0365110X52000150 / Acta Cryst. (1952)
10.1107/S0365110X54000886 / Acta Cryst. (1954)
10.1103/PhysRev.74.1168 / Phys. Rev. (1948)
{'key': '2024020819084880400_r7'}
{'key': '2024020819084880400_r8'}
{'key': '2024020819084880400_r9'}
{'key': '2024020819084880400_r10'}

Dates

Type	When
Created	20 years, 7 months ago (Jan. 5, 2005, 9:34 p.m.)
Deposited	1 year, 6 months ago (Feb. 8, 2024, 2:24 p.m.)
Indexed	1 year, 6 months ago (Feb. 10, 2024, 8:03 a.m.)
Issued	65 years, 4 months ago (April 1, 1960)
Published	65 years, 4 months ago (April 1, 1960)
Published Print	65 years, 4 months ago (April 1, 1960)

Funders 0

None

BibTeX

@article{Silver_1960, title={Nuclear Magnetic Resonance in B2O3–H2O Glasses and Boric Acids}, volume={32}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1730904}, DOI={10.1063/1.1730904}, number={4}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Silver, A. H.}, year={1960}, month=apr, pages={959–962} }

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