Abstract
The origin of irreversibility in the phenomenon of crystal diffusion is examined from a dynamical point of view. It is shown that straightforward considerations lead to the establishment of two time scales, one for jumps between lattice sites and one for vibrations about a given lattice point. The dissipation of energy is shown to occur almost entirely by relaxation of ``recaptured'' particles, little energy being lost in the transit across the barrier. The quasi-equilibrium and nonequilibrium formulations are compared and shown to be quite similar in structure and functional dependence.
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Dates
Type | When |
---|---|
Created | 20 years, 7 months ago (Jan. 5, 2005, 9:34 p.m.) |
Deposited | 1 year, 6 months ago (Feb. 8, 2024, 2:19 p.m.) |
Indexed | 1 year, 6 months ago (Feb. 9, 2024, 9:35 a.m.) |
Issued | 65 years, 4 months ago (April 1, 1960) |
Published | 65 years, 4 months ago (April 1, 1960) |
Published Print | 65 years, 4 months ago (April 1, 1960) |
@article{Rice_1960, title={Dynamical Theory of Diffusion in Crystals. IV. Some Aspects of the Introduction of Irreversibility}, volume={32}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1730845}, DOI={10.1063/1.1730845}, number={4}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Rice, Stuart A. and Frisch, Harry L.}, year={1960}, month=apr, pages={1026–1034} }