Abstract
Potential energy curves for O–N interactions corresponding to the X 2Π1/2,X 2Π3/2,A 2Σ+,B 2Π,C 2Π,D 2Σ+,E 2Σ+, and B′ 2Δ states of nitric oxide have been calculated from spectroscopic data by the Rydberg-Klein-Rees method. Curves for the 4Π, 2Σ, 4Σ, 6Σ, and 6Π states have been obtained from limited spectroscopic results and from relations derived from approximate quantum-mechanical calculations. Two semi-independent calculations have been made, and are in good agreement with each other. The quantum-mechanical relations also lead to approximate curves for the O–N2 and O2–N2 interactions over a limited range. The O2–N2 interaction is consistent with one valid at larger separation distances which has been derived from high-temperature gas viscosity data.
References
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Dates
Type | When |
---|---|
Created | 20 years, 7 months ago (Jan. 9, 2005, 8:44 a.m.) |
Deposited | 1 year, 6 months ago (Feb. 8, 2024, 2:08 p.m.) |
Indexed | 3 months, 3 weeks ago (April 27, 2025, 7:05 a.m.) |
Issued | 65 years, 11 months ago (Sept. 1, 1959) |
Published | 65 years, 11 months ago (Sept. 1, 1959) |
Published Print | 65 years, 11 months ago (Sept. 1, 1959) |
@article{Vanderslice_1959, title={Interactions between Oxygen and Nitrogen: O–N, O–N2, and O2–N2}, volume={31}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1730455}, DOI={10.1063/1.1730455}, number={3}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Vanderslice, Joseph T. and Mason, Edward A. and Maisch, William G.}, year={1959}, month=sep, pages={738–746} }