DOI: 10.1063/1.1730349. Theory of the Electron Spin Resonance of Benzene in the Triplet State

Theory of the Electron Spin Resonance of Benzene in the Triplet State

10.1063/1.1730349

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The splitting of the energy levels of the lowest triplet state of the benzene molecule has been calculated. The splittings were calculated with the aid of first-order perturbation theory from antisymmetrized wave functions, which were composed of linear combinations of Slater orbitals. In the absence of an exterior magnetic field the triplet levels are split as a consequence of the spin-spin interaction, the effect of spin-orbit interaction may be neglected. The result is a doublet and a singlet; the separation of the two levels is 0.15 cm—1 for the 3B1u state and 0.09 cm—1 for the 3B2u state.

Bibliography

Hameka, H. F. (1959). Theory of the Electron Spin Resonance of Benzene in the Triplet State. The Journal of Chemical Physics, 31(2), 315â321.

Authors 1

Hendrik F. Hameka (first)

References 16 Referenced 66

10.1021/ja01240a030 / J. Am. Chem. Soc. (1944)
10.1021/ja01222a032 / J. Am. Chem. Soc. (1945)
10.1021/ja01223a513 / J. Am. Chem. Soc. (1945)
10.1063/1.1747403 / J. Chem. Phys. (1949)
{'key': '2024020818392479700_r5'}
{'key': '2024020818392479700_r6'}
10.1038/176077a0 / Nature (1955)
10.1063/1.1744621 / J. Chem. Phys. (1958)
10.1063/1.1750138 / J. Chem. Phys. (1938)
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10.1080/00268975800100431 / Molecular Phys. (1958)
{'key': '2024020818392479700_r12'}
{'key': '2024020818392479700_r13'}
10.1051/jcp/1949460497 / J. Chim. Phys. (1949)
10.1063/1.1748095 / J. Chem. Phys. (1951)
{'key': '2024020818392479700_r16', 'first-page': '134', 'volume': 'A205', 'year': '1951', 'journal-title': 'Proc. Roy. Soc. (London)'} / Proc. Roy. Soc. (London) (1951)

Dates

Type	When
Created	20 years, 7 months ago (Jan. 9, 2005, 8:44 a.m.)
Deposited	1 year, 6 months ago (Feb. 8, 2024, 2:09 p.m.)
Indexed	1 year, 5 months ago (March 28, 2024, 4:29 a.m.)
Issued	66 years ago (Aug. 1, 1959)
Published	66 years ago (Aug. 1, 1959)
Published Print	66 years ago (Aug. 1, 1959)

Funders 0

None

BibTeX

@article{Hameka_1959, title={Theory of the Electron Spin Resonance of Benzene in the Triplet State}, volume={31}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1730349}, DOI={10.1063/1.1730349}, number={2}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Hameka, Hendrik F.}, year={1959}, month=aug, pages={315–321} }

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