DOI: 10.1063/1.1730158. Microwave Spectrum of Methyl Germane

10.1063/1.1730158

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The J=0→1 and 1→2 transitions of 28 isotopic species of CH3GeH3 have been measured. From the rotational constants obtained, the following structural parameters have been calculated: rCH=1.083±0.005 A°, rGeH=1.529±0.005 A°, rCGe=1.9453±0.0005 A°, ≰HCH=108°25′±30′, ≰HGeH=109°15′±30′. The K=1 transitions of the asymmetrically deuterated species are split by internal rotation about the C–Ge bond. Withthe assumption of a threefold sinusoidal potential, an internal barrier of 1239±25 cal/mole has been determined from these splittings. Analysis of the Stark effect of several species gives a dipole moment of 0.635±0.006 D. From observed hyperfine structure the nuclear quadrupole coupling constant of Ge73 has been calculated to be +3 Mc.

Bibliography

Laurie, V. W. (1959). Microwave Spectrum of Methyl Germane. The Journal of Chemical Physics, 30(5), 1210â1214.

Authors 1

Victor W. Laurie (first)

References 23 Referenced 126

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{'key': '2024020818290224000_r2a'}
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{'key': '2024020818290224000_r7'}
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Dates

Type	When
Created	20 years, 7 months ago (Jan. 5, 2005, 9:22 p.m.)
Deposited	1 year, 6 months ago (Feb. 8, 2024, 1:59 p.m.)
Indexed	2 months ago (July 1, 2025, 3:16 p.m.)
Issued	66 years, 4 months ago (May 1, 1959)
Published	66 years, 4 months ago (May 1, 1959)
Published Print	66 years, 4 months ago (May 1, 1959)

Funders 0

None

BibTeX

@article{Laurie_1959, title={Microwave Spectrum of Methyl Germane}, volume={30}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1730158}, DOI={10.1063/1.1730158}, number={5}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Laurie, Victor W.}, year={1959}, month=may, pages={1210–1214} }

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