DOI: 10.1063/1.1729937. Microwave Spectra of Molecules Exhibiting Internal Rotation. V. Barrier Height in Ethyl Chloride and Ethyl Bromide

Microwave Spectra of Molecules Exhibiting Internal Rotation. V. Barrier Height in Ethyl Chloride and Ethyl Bromide

10.1063/1.1729937

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The barriers to internal rotation in C2H5Cl and C2H5Br have been determined from the splittings of microwave lines in the first excited torsional state. The values obtained are V0=3560±12 cal/mole for C2H5Cl and V0=3567±30 cal/mole for C2H5Br. The influence of nuclear quadrupole hyperfine structure on the torsional splittings is discussed.

Bibliography

Lide, D. R. (1959). Microwave Spectra of Molecules Exhibiting Internal Rotation. V. Barrier Height in Ethyl Chloride and Ethyl Bromide. The Journal of Chemical Physics, 30(1), 37â39.

Authors 1

David R. Lide (first)

References 10 Referenced 48

10.1063/1.1743588 / J. Chem. Phys. (1957)
10.1063/1.1743589 / J. Chem. Phys. (1957)
10.1063/1.1743867 / J. Chem. Phys. (1957)
10.1063/1.1743727 / J. Chem. Phys. (1957)
{'key': '2024020818143337300_r5'}
10.1063/1.1744588 / J. Chem. Phys. (1958)
10.1063/1.1740386 / J. Chem. Phys. (1954)
10.1039/df9511000066 / Discussions Faraday Soc. (1951)
{'key': '2024020818143337300_r9', 'first-page': '358', 'volume': '25', 'year': '1956', 'journal-title': 'J. Chem. Phys.'} / J. Chem. Phys. (1956)
{'key': '2024020818143337300_r10'}

Dates

Type	When
Created	20 years, 7 months ago (Jan. 5, 2005, 9:22 p.m.)
Deposited	1 year, 6 months ago (Feb. 8, 2024, 1:53 p.m.)
Indexed	1 year, 6 months ago (Feb. 9, 2024, 3:18 a.m.)
Issued	66 years, 7 months ago (Jan. 1, 1959)
Published	66 years, 7 months ago (Jan. 1, 1959)
Published Print	66 years, 7 months ago (Jan. 1, 1959)

Funders 0

None

BibTeX

@article{Lide_1959, title={Microwave Spectra of Molecules Exhibiting Internal Rotation. V. Barrier Height in Ethyl Chloride and Ethyl Bromide}, volume={30}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1729937}, DOI={10.1063/1.1729937}, number={1}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Lide, David R.}, year={1959}, month=jan, pages={37–39} }

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