DOI: 10.1063/1.1728310. Determination of functional center local environment in copper-modified Pb[Zr0.54Ti0.46]O3 ceramics

Determination of functional center local environment in copper-modified Pb[Zr0.54Ti0.46]O3 ceramics

10.1063/1.1728310

Crossref journal-article

AIP Publishing

Journal of Applied Physics (317)

Abstract

Ferroelectric copper(II)-modified polycrystalline Pb[Zr0.54Ti0.46]O3 ceramics with a dopant concentration of 0.25 mol % were investigated by means of electron paramagnetic resonance and hyperfine sublevel correlation spectroscopy. Special emphasis was put on the resolution of the Pb207 hyperfine couplings, which were resolved in the first and second coordination sphere. The results prove that copper is incorporated at the octahedrally coordinated [Zr,Ti] site, acting as an acceptor and disfavor a directly coordinated oxygen vacancy to the copper center for charge compensation.

Bibliography

Eichel, R.-A., Kungl, H., & Hoffmann, M. J. (2004). Determination of functional center local environment in copper-modified Pb[Zr0.54Ti0.46]O3 ceramics. Journal of Applied Physics, 95(12), 8092â8096.

Authors 3

Rüdiger-A. Eichel (first)
Hans Kungl (additional)
Michael J. Hoffmann (additional)

References 10 Referenced 30

10.1016/0022-3697(96)00021-2 / J. Phys. Chem. Solids (1996)
10.1111/j.1151-2916.1997.tb02884.x / J. Am. Ceram. Soc. (1997)
10.1007/s003390050712 / Appl. Phys. A: Mater. Sci. Process. (1998)
10.1016/0009-2614(86)80124-5 / Chem. Phys. Lett. (1986)
10.1016/0022-2364(90)90181-8 / J. Magn. Reson. (1969-1992) (1990)
10.1016/0009-2614(86)80398-0 / Chem. Phys. Lett. (1986)
{'key': '2024020718564131800_r7', 'first-page': '2625', 'volume': '8', 'year': '1996', 'journal-title': 'J. Phys.: Condens. Matter'} / J. Phys.: Condens. Matter (1996)
{'key': '2024020718564131800_r7a', 'first-page': '3779', 'volume': '9', 'year': '1997', 'journal-title': 'J. Phys.: Condens. Matter'} / J. Phys.: Condens. Matter (1997)
10.1007/s100510170109 / Eur. Phys. J. B (2001)
10.1021/jp9525999 / J. Phys. Chem. (1996)

Dates

Type	When
Created	21 years, 3 months ago (May 28, 2004, 6:01 p.m.)
Deposited	1 year, 6 months ago (Feb. 7, 2024, 7:33 p.m.)
Indexed	3 months ago (May 27, 2025, 1:08 a.m.)
Issued	21 years, 2 months ago (June 15, 2004)
Published	21 years, 2 months ago (June 15, 2004)
Published Print	21 years, 2 months ago (June 15, 2004)

Funders 0

None

BibTeX

@article{Eichel_2004, title={Determination of functional center local environment in copper-modified Pb[Zr0.54Ti0.46]O3 ceramics}, volume={95}, ISSN={1089-7550}, url={http://dx.doi.org/10.1063/1.1728310}, DOI={10.1063/1.1728310}, number={12}, journal={Journal of Applied Physics}, publisher={AIP Publishing}, author={Eichel, Rüdiger-A. and Kungl, Hans and Hoffmann, Michael J.}, year={2004}, month=jun, pages={8092–8096} }

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