DOI: 10.1063/1.1728057. Adiabatic Dissociation Energies for the Ground States of the H2, HD, and D2 Molecules

Adiabatic Dissociation Energies for the Ground States of the H2, HD, and D2 Molecules

10.1063/1.1728057

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

Variational adiabatic potential curves for the ground state X 1Σg of these molecules were constructed from the adiabatic coupling corrections computed by Kol/os and Wolniewicz. Energy eigenvalues of these variational potentials were computed. The derived dissociation energies are still larger than those inferred from the spectra of the molecules. It is suggested that the resolution of this discrepancy is more likely to be found in a reinterpretation of the experimental data than through any refinement of theoretical calculations.

Bibliography

Hunter, G. (1966). Adiabatic Dissociation Energies for the Ground States of the H2, HD, and D2 Molecules. The Journal of Chemical Physics, 45(8), 3022â3028.

Authors 1

G. Hunter (first)

References 17 Referenced 18

10.1103/RevModPhys.32.219 / Rev. Mod. Phys. (1960)
10.1103/RevModPhys.35.473 / Rev. Mod. Phys. (1963)
10.1063/1.1725796 / J. Chem. Phys. (1964)
10.1063/1.1725797 / J. Chem. Phys. (1964)
10.1063/1.1697142 / J. Chem. Phys. (1965)
{'key': '2024020901362669300_r6', 'first-page': '482', 'volume': '5', 'year': '1960', 'journal-title': 'J. Mol. Spectry.'} / J. Mol. Spectry. (1960)
10.1139/p60-086 / Can. J. Phys. (1960)
10.1016/0022-2852(65)90146-3 / J. Mol. Spectry. (1965)
{'key': '2024020901362669300_r9', 'first-page': '3340', 'volume': '43', 'year': '1965', 'journal-title': 'J. Chem. Phys.'} / J. Chem. Phys. (1965)
{'key': '2024020901362669300_r10'}
{'key': '2024020901362669300_r11', 'first-page': '383', 'volume': 'A237', 'year': '1956', 'journal-title': 'Proc. Roy. Soc. (London)'} / Proc. Roy. Soc. (London) (1956)
{'key': '2024020901362669300_r12'}
{'key': '2024020901362669300_r13'}
{'key': '2024020901362669300_r14'}
{'key': '2024020901362669300_r15'}
10.1103/PhysRev.126.1470 / Phys. Rev. (1962)
10.1063/1.1696984 / J. Chem. Phys. (1965)

Dates

Type	When
Created	20 years, 7 months ago (Jan. 9, 2005, 4:42 a.m.)
Deposited	1 year, 6 months ago (Feb. 8, 2024, 8:36 p.m.)
Indexed	1 month, 3 weeks ago (July 2, 2025, 3:28 p.m.)
Issued	58 years, 10 months ago (Oct. 15, 1966)
Published	58 years, 10 months ago (Oct. 15, 1966)
Published Print	58 years, 10 months ago (Oct. 15, 1966)

Funders 0

None

BibTeX

@article{Hunter_1966, title={Adiabatic Dissociation Energies for the Ground States of the H2, HD, and D2 Molecules}, volume={45}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1728057}, DOI={10.1063/1.1728057}, number={8}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Hunter, G.}, year={1966}, month=oct, pages={3022–3028} }

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