DOI: 10.1063/1.1727972. Electronic Spectrum of Ethylene Single Crystal; Search for the Olefin Mystery Band

Electronic Spectrum of Ethylene Single Crystal; Search for the Olefin Mystery Band

10.1063/1.1727972

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

Ethylene single crystals have been grown as uv specimens. The near-uv spectrum (2000–2500 Å) consists of a number of bands quite analogous to the π—π* (N–V) transition in the gas-phase molecule. No drastic perturbations are observed. No additional electronic transition (e.g., CH*—π, n—π*) is observed in this region, in spite of the relaxation of selection rules in the crystalline site (Ci). Thus, if the ``mystery'' band (6 eV) exists at all, its excited state is most likely either a triplet state or a Rydberg-type state (or a combination of both).

Bibliography

Lubezky, A., & Kopelman, R. (1966). Electronic Spectrum of Ethylene Single Crystal; Search for the Olefin Mystery Band. The Journal of Chemical Physics, 45(7), 2526â2528.

Authors 2

A. Lubezky (first)
R. Kopelman (additional)

References 32 Referenced 14

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Dates

Type	When
Created	20 years, 7 months ago (Jan. 9, 2005, 4:42 a.m.)
Deposited	1 year, 6 months ago (Feb. 8, 2024, 8:22 p.m.)
Indexed	1 year, 6 months ago (Feb. 9, 2024, 4:46 a.m.)
Issued	58 years, 10 months ago (Oct. 1, 1966)
Published	58 years, 10 months ago (Oct. 1, 1966)
Published Print	58 years, 10 months ago (Oct. 1, 1966)

Funders 0

None

BibTeX

@article{Lubezky_1966, title={Electronic Spectrum of Ethylene Single Crystal; Search for the Olefin Mystery Band}, volume={45}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1727972}, DOI={10.1063/1.1727972}, number={7}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Lubezky, A. and Kopelman, R.}, year={1966}, month=oct, pages={2526–2528} }

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