DOI: 10.1063/1.1727897. Monte Carlo Studies of Lattice-Model Polymer Chains. II. End-to-End Length

Monte Carlo Studies of Lattice-Model Polymer Chains. II. End-to-End Length

10.1063/1.1727897

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The relaxation and the equilibrium behavior of lattice-model polymer chains are studied by simulation on a digital computer. Results are presented for the behavior of the square of end-to-end length l2 for chains of 8, 16, 32, and 64 beads, with and without excluded volume restrictions. It is found that the relaxation of the lattice-model chains without excluded volume is remarkably similar to that of statistical-bead models. The introduction of excluded volume restrictions causes drastic qualitative changes in the relaxation behavior of the longer chains, and lengthens the time required for their relaxation by factors of up to 15. While the distribution in l2 for the longer chains with excluded volume departs noticeably from Gaussian form at quite small and quite large values of l2, it appears close to Gaussian in a range from one-third to three times the mean-square value of l2.

Bibliography

Verdier, P. H. (1966). Monte Carlo Studies of Lattice-Model Polymer Chains. II. End-to-End Length. The Journal of Chemical Physics, 45(6), 2122â2128.

Authors 1

Peter H. Verdier (first)

References 21 Referenced 69

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10.1063/1.1742462 / J. Chem. Phys. (1956)
10.1143/PTPS.10.56 / Progr. Theoret. Phys. (Kyoto) Suppl. (1959)
10.1063/1.1727896 / J. Chem. Phys. (1966)
10.1063/1.1695847 / J. Chem. Phys. (1965)
10.1063/1.1695848 / J. Chem. Phys. (1965)
10.1063/1.1732301 / J. Chem. Phys. (1962)
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10.1146/annurev.pc.16.100165.000435 / Ann. Rev. Phys. Chem. (1965)
{'key': '2024020901223162100_r8'}
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10.1017/S0305004100036240 / Proc. Cambridge Phil. Soc. (1962)
10.1063/1.1733626 / J. Chem. Phys. (1963)
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10.1002/pol.1962.1205716526 / J. Polymer Sci. (1962)
10.1063/1.1733953 / J. Chem. Phys. (1963)
10.1088/0370-1328/85/4/302 / Proc. Phys. Soc. (London) (1965)
10.6028/jres.069A.036 / J. Res. Natl. Bur. Std. (U.S.) (1965)

Dates

Type	When
Created	20 years, 7 months ago (Jan. 9, 2005, 4:42 a.m.)
Deposited	1 year, 6 months ago (Feb. 8, 2024, 8:22 p.m.)
Indexed	1 year, 6 months ago (Feb. 10, 2024, 8:38 p.m.)
Issued	58 years, 11 months ago (Sept. 15, 1966)
Published	58 years, 11 months ago (Sept. 15, 1966)
Published Print	58 years, 11 months ago (Sept. 15, 1966)

Funders 0

None

BibTeX

@article{Verdier_1966, title={Monte Carlo Studies of Lattice-Model Polymer Chains. II. End-to-End Length}, volume={45}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1727897}, DOI={10.1063/1.1727897}, number={6}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Verdier, Peter H.}, year={1966}, month=sep, pages={2122–2128} }

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