DOI: 10.1063/1.1727062. Mass-Spectrometric Studies of Reactions in Flames. II. Quantitative Sampling of Free Radicals from One-Atmosphere Flames

Mass-Spectrometric Studies of Reactions in Flames. II. Quantitative Sampling of Free Radicals from One-Atmosphere Flames

10.1063/1.1727062

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

Direct mass spectrometric sampling studies of one-atmosphere flames are described. A simple model of the sampling process is summarized which accounts for the effects and results obtained. Stable product analysis and evidence for appreciable temperature dependence of fragmentation patterns are shown. Quantitative sampling of the free radicals H, O, OH, and Cl from the burnt gas region of one-atmosphere flames is demonstrated, with direct observation of excess free-radical concentrations in the reaction zones of these flames.

Bibliography

Milne, T. A., & Greene, F. T. (1966). Mass-Spectrometric Studies of Reactions in Flames. II. Quantitative Sampling of Free Radicals from One-Atmosphere Flames. The Journal of Chemical Physics, 44(6), 2444â2449.

Authors 2

Thomas A. Milne (first)
Frank T. Greene (additional)

References 19 Referenced 35

10.1063/1.1725351 / J. Chem. Phys. (1964)
{'key': '2024020900403578500_r2'}
{'key': '2024020900403578500_r3'}
{'key': '2024020900403578500_r4'}
{'key': '2024020900403578500_r5'}
{'key': '2024020900403578500_r6'}
10.1139/v64-041 / Can. J. Chem. (1964)
10.1139/v65-002 / Can. J. Chem. (1965)
{'key': '2024020900403578500_r8'}
{'key': '2024020900403578500_r9', 'first-page': '751', 'volume': '17', 'year': '1964', 'journal-title': 'Appl. Mech. Rev.'} / Appl. Mech. Rev. (1964)
10.2514/3.3044 / AIAA J. (1965)
10.1063/1.1734160 / J. Chem. Phys. (1963)
{'key': '2024020900403578500_r12', 'first-page': '409', 'volume': '280A', 'year': '1964', 'journal-title': 'Proc. Roy. Soc. (London)'} / Proc. Roy. Soc. (London) (1964)
{'key': '2024020900403578500_r13'}
{'key': '2024020900403578500_r14'}
{'key': '2024020900403578500_r15', 'first-page': '248', 'volume': 'A248', 'year': '1958', 'journal-title': 'Proc. Roy. Soc. (London)'} / Proc. Roy. Soc. (London) (1958)
10.1139/v60-245 / Can. J. Chem. (1960)
{'key': '2024020900403578500_r17', 'first-page': '89', 'volume': 'A235', 'year': '1956', 'journal-title': 'Proc. Roy. Soc. (London)'} / Proc. Roy. Soc. (London) (1956)
10.1103/PhysRev.113.815 / Phys. Rev. (1959)

Dates

Type	When
Created	20 years, 7 months ago (Jan. 9, 2005, 3:17 a.m.)
Deposited	1 year, 6 months ago (Feb. 8, 2024, 7:40 p.m.)
Indexed	1 year ago (Aug. 31, 2024, 5:27 a.m.)
Issued	59 years, 5 months ago (March 15, 1966)
Published	59 years, 5 months ago (March 15, 1966)
Published Print	59 years, 5 months ago (March 15, 1966)

Funders 0

None

BibTeX

@article{Milne_1966, title={Mass-Spectrometric Studies of Reactions in Flames. II. Quantitative Sampling of Free Radicals from One-Atmosphere Flames}, volume={44}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1727062}, DOI={10.1063/1.1727062}, number={6}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Milne, Thomas A. and Greene, Frank T.}, year={1966}, month=mar, pages={2444–2449} }

JSON

{
  "indexed": {
    "date-parts": [
      [
        2024,
        8,
        31
      ]
    ],
    "date-time": "2024-08-31T09:27:19Z",
    "timestamp": 1725096439280
  },
  "reference-count": 19,
  "publisher": "AIP Publishing",
  "issue": "6",
  "content-domain": {
    "domain": [
      "pubs.aip.org"
    ],
    "crossmark-restriction": true
  },
  "published-print": {
    "date-parts": [
      [
        1966,
        3,
        15
      ]
    ]
  },
  "abstract": "<jats:p>Direct mass spectrometric sampling studies of one-atmosphere flames are described. A simple model of the sampling process is summarized which accounts for the effects and results obtained. Stable product analysis and evidence for appreciable temperature dependence of fragmentation patterns are shown. Quantitative sampling of the free radicals H, O, OH, and Cl from the burnt gas region of one-atmosphere flames is demonstrated, with direct observation of excess free-radical concentrations in the reaction zones of these flames.</jats:p>",
  "DOI": "10.1063/1.1727062",
  "type": "journal-article",
  "created": {
    "date-parts": [
      [
        2005,
        1,
        9
      ]
    ],
    "date-time": "2005-01-09T08:17:14Z",
    "timestamp": 1105258634000
  },
  "page": "2444-2449",
  "update-policy": "http://dx.doi.org/10.1063/aip-crossmark-policy-page",
  "source": "Crossref",
  "is-referenced-by-count": 35,
  "title": "Mass-Spectrometric Studies of Reactions in Flames. II. Quantitative Sampling of Free Radicals from One-Atmosphere Flames",
  "prefix": "10.1063",
  "volume": "44",
  "author": [
    {
      "given": "Thomas A.",
      "family": "Milne",
      "sequence": "first",
      "affiliation": [
        {
          "name": "Midwest Research Institute, Kansas City, Missouri"
        }
      ]
    },
    {
      "given": "Frank T.",
      "family": "Greene",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Midwest Research Institute, Kansas City, Missouri"
        }
      ]
    }
  ],
  "member": "317",
  "reference": [
    {
      "key": "2024020900403578500_r1",
      "doi-asserted-by": "crossref",
      "first-page": "1488",
      "DOI": "10.1063/1.1725351",
      "volume": "40",
      "year": "1964",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020900403578500_r2"
    },
    {
      "key": "2024020900403578500_r3"
    },
    {
      "key": "2024020900403578500_r4"
    },
    {
      "key": "2024020900403578500_r5"
    },
    {
      "key": "2024020900403578500_r6"
    },
    {
      "key": "2024020900403578500_r7",
      "doi-asserted-by": "crossref",
      "first-page": "225",
      "DOI": "10.1139/v64-041",
      "volume": "42",
      "year": "1964",
      "journal-title": "Can. J. Chem."
    },
    {
      "key": "2024020900403578500_r7a",
      "doi-asserted-by": "crossref",
      "first-page": "6",
      "DOI": "10.1139/v65-002",
      "volume": "43",
      "year": "1965",
      "journal-title": "Can. J. Chem."
    },
    {
      "key": "2024020900403578500_r8"
    },
    {
      "key": "2024020900403578500_r9",
      "first-page": "751",
      "volume": "17",
      "year": "1964",
      "journal-title": "Appl. Mech. Rev."
    },
    {
      "key": "2024020900403578500_r10",
      "doi-asserted-by": "crossref",
      "first-page": "993",
      "DOI": "10.2514/3.3044",
      "volume": "3",
      "year": "1965",
      "journal-title": "AIAA J."
    },
    {
      "key": "2024020900403578500_r11",
      "doi-asserted-by": "crossref",
      "first-page": "3150",
      "DOI": "10.1063/1.1734160",
      "volume": "39",
      "year": "1963",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020900403578500_r12",
      "first-page": "409",
      "volume": "280A",
      "year": "1964",
      "journal-title": "Proc. Roy. Soc. (London)"
    },
    {
      "key": "2024020900403578500_r13"
    },
    {
      "key": "2024020900403578500_r14"
    },
    {
      "key": "2024020900403578500_r15",
      "first-page": "248",
      "volume": "A248",
      "year": "1958",
      "journal-title": "Proc. Roy. Soc. (London)"
    },
    {
      "key": "2024020900403578500_r16",
      "doi-asserted-by": "crossref",
      "first-page": "1804",
      "DOI": "10.1139/v60-245",
      "volume": "38",
      "year": "1960",
      "journal-title": "Can. J. Chem."
    },
    {
      "key": "2024020900403578500_r17",
      "first-page": "89",
      "volume": "A235",
      "year": "1956",
      "journal-title": "Proc. Roy. Soc. (London)"
    },
    {
      "key": "2024020900403578500_r18",
      "doi-asserted-by": "crossref",
      "first-page": "815",
      "DOI": "10.1103/PhysRev.113.815",
      "volume": "113",
      "year": "1959",
      "journal-title": "Phys. Rev."
    }
  ],
  "container-title": "The Journal of Chemical Physics",
  "original-title": [],
  "language": "en",
  "link": [
    {
      "URL": "https://pubs.aip.org/aip/jcp/article-pdf/44/6/2444/18842388/2444_1_online.pdf",
      "content-type": "application/pdf",
      "content-version": "vor",
      "intended-application": "syndication"
    },
    {
      "URL": "https://pubs.aip.org/aip/jcp/article-pdf/44/6/2444/18842388/2444_1_online.pdf",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "similarity-checking"
    }
  ],
  "deposited": {
    "date-parts": [
      [
        2024,
        2,
        9
      ]
    ],
    "date-time": "2024-02-09T00:40:47Z",
    "timestamp": 1707439247000
  },
  "score": 1,
  "resource": {
    "primary": {
      "URL": "https://pubs.aip.org/jcp/article/44/6/2444/81503/Mass-Spectrometric-Studies-of-Reactions-in-Flames"
    }
  },
  "subtitle": [],
  "short-title": [],
  "issued": {
    "date-parts": [
      [
        1966,
        3,
        15
      ]
    ]
  },
  "references-count": 19,
  "journal-issue": {
    "issue": "6",
    "published-print": {
      "date-parts": [
        [
          1966,
          3,
          15
        ]
      ]
    }
  },
  "URL": "http://dx.doi.org/10.1063/1.1727062",
  "relation": {},
  "ISSN": [
    "0021-9606",
    "1089-7690"
  ],
  "subject": [],
  "published-other": {
    "date-parts": [
      [
        1966,
        3,
        15
      ]
    ]
  },
  "published": {
    "date-parts": [
      [
        1966,
        3,
        15
      ]
    ]
  }
}