DOI: 10.1063/1.1726961. Infrared Spectrum of Carbon Dioxide Anion Radical

Infrared Spectrum of Carbon Dioxide Anion Radical

10.1063/1.1726961

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

Pressed alkali halide disks of infrared spectroscopy have been used as matrices to trap and to stabilize the carbon dioxide anion free radical. The radical was generated by exposing disks containing the formate ion in solid solution to gamma rays from a cobalt source. The ESR, the ultraviolet, and the infrared spectra of the radical have been identified. From the carbon−12 and −13 isotopic frequencies of the antisymmetric CO-bond stretching infrared band, a valence angle of 127°±8° was calculated for this radical. The radical reacted with water to produce bicarbonate and formate ions.

Bibliography

Hartman, K. O., & Hisatsune, I. C. (1966). Infrared Spectrum of Carbon Dioxide Anion Radical. The Journal of Chemical Physics, 44(5), 1913â1918.

Authors 2

K. O. Hartman (first)
I. C. Hisatsune (additional)

References 11 Referenced 118

10.1080/00268976100100181 / Mol. Phys. (1961)
10.1021/j100891a006 / J. Phys. Chem. (1965)
10.1080/00268976200100191 / Mol. Phys. (1962)
10.1021/j100886a037 / J. Phys. Chem. (1965)
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10.1063/1.1695761 / J. Chem. Phys. (1965)
10.1080/00268976400100271 / Mol. Phys. (1964)
10.1021/cr60230a005 / Chem. Rev. (1964)
10.1103/RevModPhys.24.79 / Rev. Mod. Phys. (1952)
{'key': '2024020900344209500_r10'}
10.1126/science.145.3639.1455 / Science (1964)

Dates

Type	When
Created	20 years, 7 months ago (Jan. 9, 2005, 3:17 a.m.)
Deposited	1 year, 6 months ago (Feb. 8, 2024, 7:34 p.m.)
Indexed	2 months ago (July 3, 2025, 3:32 a.m.)
Issued	59 years, 6 months ago (March 1, 1966)
Published	59 years, 6 months ago (March 1, 1966)
Published Print	59 years, 6 months ago (March 1, 1966)

Funders 0

None

BibTeX

@article{Hartman_1966, title={Infrared Spectrum of Carbon Dioxide Anion Radical}, volume={44}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1726961}, DOI={10.1063/1.1726961}, number={5}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Hartman, K. O. and Hisatsune, I. C.}, year={1966}, month=mar, pages={1913–1918} }

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