DOI: 10.1063/1.1726504. Sign of <i>J</i>HF in CHFCl2

10.1063/1.1726504

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

If a nuclear spin is relaxed by two relaxation mechanisms with the same correlation time, the NMR lines may have differing relaxation rates. The fluorine nuclear spin in CHFCl2 at low temperature is relaxed by dipole—dipole interaction and by an anisotropy in the chemical shift. The sign of the coupling constant between fluorine and hydrogen (JHF) has been determined from the relaxation pattern. JHF turns out to be positive.

Bibliography

Mackor, E. L., & MacLean, C. (1966). Sign of JHF in CHFCl2. The Journal of Chemical Physics, 44(1), 64â69.

Authors 2

E. L. Mackor (first)
C. MacLean (additional)

References 23 Referenced 73

{'key': '2024020900282986600_r1'}
10.1103/PhysRevLett.11.462 / Phys. Rev. Letters (1963)
10.1063/1.1725007 / J. Chem. Phys. (1964)
10.1063/1.1743033 / J. Chem. Phys. (1956)
10.1063/1.1739849 / J. Chem. Phys. (1954)
10.1147/rd.11.0019 / IBM J. Res. Develop. (1957)
{'key': '2024020900282986600_r6a'}
{'key': '2024020900282986600_r6b'}
10.1063/1.1733499 / J. Chem. Phys. (1963)
10.1103/PhysRev.99.559 / Phys. Rev. (1955)
10.1063/1.1742867 / J. Chem. Phys. (1956)
10.1063/1.1695928 / J. Chem. Phys. (1965)
10.1063/1.1701036 / J. Chem. Phys. (1961)
10.1088/0370-1328/81/6/302 / Proc. Phys. Soc. (London) (1963)
10.1063/1.1725873 / J. Chem. Phys. (1964)
{'key': '2024020900282986600_r13'}
10.1063/1.1696428 / J. Chem. Phys. (1965)
{'key': '2024020900282986600_r15', 'first-page': '571', 'volume': '42', 'year': '1965', 'journal-title': 'J. Chem. Phys.'} / J. Chem. Phys. (1965)
{'key': '2024020900282986600_r16'}
10.1021/ja00879a041 / J. Am. Chem. Soc. (1962)
{'key': '2024020900282986600_r17a', 'first-page': '1373', 'volume': '85', 'year': '1963', 'journal-title': 'J. Am. Chem. Soc.'} / J. Am. Chem. Soc. (1963)
{'key': '2024020900282986600_r18'}
10.1021/ja00871a044 / J. Am. Chem. Soc. (1962)

Dates

Type	When
Created	20 years, 7 months ago (Jan. 9, 2005, 3:17 a.m.)
Deposited	1 year, 6 months ago (Feb. 8, 2024, 7:28 p.m.)
Indexed	2 months ago (July 2, 2025, 2:46 p.m.)
Issued	59 years, 8 months ago (Jan. 1, 1966)
Published	59 years, 8 months ago (Jan. 1, 1966)
Published Print	59 years, 8 months ago (Jan. 1, 1966)

Funders 0

None

BibTeX

@article{Mackor_1966, title={Sign of JHF in CHFCl2}, volume={44}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1726504}, DOI={10.1063/1.1726504}, number={1}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Mackor, E. L. and MacLean, C.}, year={1966}, month=jan, pages={64–69} }

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